Synthesis and Swelling Behaviors of Microcrystal Muscovite Composite Superabsorbent by Photopolymerization

A new microcrystal muscovite composite superabsorbent was synthesized by UV photopolymerization using 2-hydroxy-2-methylpropiophenone(1 173) as photoinitiator,N,N-methylene bisacrylamide(MBA) as crosslinker,acrylic acid(AA),acrylamide(AM) and sodium 4-styrenesulfonate(SSS) as comonomers.Factors affe...

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Veröffentlicht in:Journal of Wuhan University of Technology. Materials science edition 2016-02, Vol.31 (1), p.151-156
Hauptverfasser: Wan, Tao, Liao, Ling, Huang, Runqiu, Wu, Daqing, Tang, Li, Xiong, Jing, Chen, Qiaohe
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container_issue 1
container_start_page 151
container_title Journal of Wuhan University of Technology. Materials science edition
container_volume 31
creator Wan, Tao
Liao, Ling
Huang, Runqiu
Wu, Daqing
Tang, Li
Xiong, Jing
Chen, Qiaohe
description A new microcrystal muscovite composite superabsorbent was synthesized by UV photopolymerization using 2-hydroxy-2-methylpropiophenone(1 173) as photoinitiator,N,N-methylene bisacrylamide(MBA) as crosslinker,acrylic acid(AA),acrylamide(AM) and sodium 4-styrenesulfonate(SSS) as comonomers.Factors affecting water and salt absorption of the microcrystal muscovite composite superabsorbent,such as crosslinker amount,microcrystal muscovite concentration,photoinitiator content,and SSS concentration,were systematically studied.Water retention capacity of the composite superabsorbent was also investigated.The results show that microcrystal muscovite composite superabsorbent has water absorbency of 550 g/g,salt absorbency of 62 g/g,and water retention of 60% after heating at 70 ℃ for 40 h.The microcrystal muscovite is physically combined into the polymeric network without destroying its polycrystalline structure and the surface of the microcrystal muscovite composite superabsorbent has some deep and small holes.
doi_str_mv 10.1007/s11595-016-1345-4
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subjects Chemistry and Materials Science
Crosslinking
Materials Science
Mica
Microcrystals
Muscovite
Orgamic Materials
Photoinitiators
Photopolymerization
Sodium
Swelling
亚甲基双丙烯酰胺
交联剂用量
合成
复合高吸水性树脂
对苯乙烯磺酸钠
微晶白云母
溶胀性能
紫外光聚合
title Synthesis and Swelling Behaviors of Microcrystal Muscovite Composite Superabsorbent by Photopolymerization
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