Synthesis and Swelling Behaviors of Microcrystal Muscovite Composite Superabsorbent by Photopolymerization
A new microcrystal muscovite composite superabsorbent was synthesized by UV photopolymerization using 2-hydroxy-2-methylpropiophenone(1 173) as photoinitiator,N,N-methylene bisacrylamide(MBA) as crosslinker,acrylic acid(AA),acrylamide(AM) and sodium 4-styrenesulfonate(SSS) as comonomers.Factors affe...
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Veröffentlicht in: | Journal of Wuhan University of Technology. Materials science edition 2016-02, Vol.31 (1), p.151-156 |
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creator | Wan, Tao Liao, Ling Huang, Runqiu Wu, Daqing Tang, Li Xiong, Jing Chen, Qiaohe |
description | A new microcrystal muscovite composite superabsorbent was synthesized by UV photopolymerization using 2-hydroxy-2-methylpropiophenone(1 173) as photoinitiator,N,N-methylene bisacrylamide(MBA) as crosslinker,acrylic acid(AA),acrylamide(AM) and sodium 4-styrenesulfonate(SSS) as comonomers.Factors affecting water and salt absorption of the microcrystal muscovite composite superabsorbent,such as crosslinker amount,microcrystal muscovite concentration,photoinitiator content,and SSS concentration,were systematically studied.Water retention capacity of the composite superabsorbent was also investigated.The results show that microcrystal muscovite composite superabsorbent has water absorbency of 550 g/g,salt absorbency of 62 g/g,and water retention of 60% after heating at 70 ℃ for 40 h.The microcrystal muscovite is physically combined into the polymeric network without destroying its polycrystalline structure and the surface of the microcrystal muscovite composite superabsorbent has some deep and small holes. |
doi_str_mv | 10.1007/s11595-016-1345-4 |
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Materials science edition</title><addtitle>J. Wuhan Univ. Technol.-Mat. Sci. Edit</addtitle><addtitle>Journal of Wuhan University of Technology. Materials Science Edition</addtitle><description>A new microcrystal muscovite composite superabsorbent was synthesized by UV photopolymerization using 2-hydroxy-2-methylpropiophenone(1 173) as photoinitiator,N,N-methylene bisacrylamide(MBA) as crosslinker,acrylic acid(AA),acrylamide(AM) and sodium 4-styrenesulfonate(SSS) as comonomers.Factors affecting water and salt absorption of the microcrystal muscovite composite superabsorbent,such as crosslinker amount,microcrystal muscovite concentration,photoinitiator content,and SSS concentration,were systematically studied.Water retention capacity of the composite superabsorbent was also investigated.The results show that microcrystal muscovite composite superabsorbent has water absorbency of 550 g/g,salt absorbency of 62 g/g,and water retention of 60% after heating at 70 ℃ for 40 h.The microcrystal muscovite is physically combined into the polymeric network without destroying its polycrystalline structure and the surface of the microcrystal muscovite composite superabsorbent has some deep and small holes.</description><subject>Chemistry and Materials Science</subject><subject>Crosslinking</subject><subject>Materials Science</subject><subject>Mica</subject><subject>Microcrystals</subject><subject>Muscovite</subject><subject>Orgamic Materials</subject><subject>Photoinitiators</subject><subject>Photopolymerization</subject><subject>Sodium</subject><subject>Swelling</subject><subject>亚甲基双丙烯酰胺</subject><subject>交联剂用量</subject><subject>合成</subject><subject>复合高吸水性树脂</subject><subject>对苯乙烯磺酸钠</subject><subject>微晶白云母</subject><subject>溶胀性能</subject><subject>紫外光聚合</subject><issn>1000-2413</issn><issn>1993-0437</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kE1v1DAQhiMEEqXwA7hZcOGS4vFX7COsClRqBdLC2XISZ9errJ16kqLw6_FqK4Q4cPIcnvcdz1NVr4FeAaXNewSQRtYUVA1cyFo8qS7AGF5TwZunZaaU1kwAf169QDxQKihX6qI6bNc47z0GJC72ZPvTj2OIO_LR791DSBlJGshd6HLq8oqzG8ndgl16CLMnm3ScEp6m7TL57FpMufVxJu1Kvu3TnKY0rkefwy83hxRfVs8GN6J_9fheVj8-XX_ffKlvv36-2Xy4rTveqLnuHPCe96JnmrVt02smnGwG6JXTTGltlJbSNS3rJcimY46Z1rsOhBB6MIryy-rduXfK6X7xONtjwK7c5aJPC1poDGdcaSML-vYf9JCWHMvvCqXAFNKcCuFMFQuI2Q92yuHo8mqB2pN9e7Zvi317sm9FybBzBgsbdz7_1fyf0JvHRfsUd_cl92eTUhqoERz4b4ySlFA</recordid><startdate>20160201</startdate><enddate>20160201</enddate><creator>Wan, Tao</creator><creator>Liao, Ling</creator><creator>Huang, Runqiu</creator><creator>Wu, Daqing</creator><creator>Tang, Li</creator><creator>Xiong, Jing</creator><creator>Chen, Qiaohe</creator><general>Wuhan University of Technology</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W92</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8AO</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20160201</creationdate><title>Synthesis and Swelling Behaviors of Microcrystal Muscovite Composite Superabsorbent by Photopolymerization</title><author>Wan, Tao ; 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Materials science edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wan, Tao</au><au>Liao, Ling</au><au>Huang, Runqiu</au><au>Wu, Daqing</au><au>Tang, Li</au><au>Xiong, Jing</au><au>Chen, Qiaohe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Swelling Behaviors of Microcrystal Muscovite Composite Superabsorbent by Photopolymerization</atitle><jtitle>Journal of Wuhan University of Technology. Materials science edition</jtitle><stitle>J. Wuhan Univ. Technol.-Mat. Sci. Edit</stitle><addtitle>Journal of Wuhan University of Technology. Materials Science Edition</addtitle><date>2016-02-01</date><risdate>2016</risdate><volume>31</volume><issue>1</issue><spage>151</spage><epage>156</epage><pages>151-156</pages><issn>1000-2413</issn><eissn>1993-0437</eissn><abstract>A new microcrystal muscovite composite superabsorbent was synthesized by UV photopolymerization using 2-hydroxy-2-methylpropiophenone(1 173) as photoinitiator,N,N-methylene bisacrylamide(MBA) as crosslinker,acrylic acid(AA),acrylamide(AM) and sodium 4-styrenesulfonate(SSS) as comonomers.Factors affecting water and salt absorption of the microcrystal muscovite composite superabsorbent,such as crosslinker amount,microcrystal muscovite concentration,photoinitiator content,and SSS concentration,were systematically studied.Water retention capacity of the composite superabsorbent was also investigated.The results show that microcrystal muscovite composite superabsorbent has water absorbency of 550 g/g,salt absorbency of 62 g/g,and water retention of 60% after heating at 70 ℃ for 40 h.The microcrystal muscovite is physically combined into the polymeric network without destroying its polycrystalline structure and the surface of the microcrystal muscovite composite superabsorbent has some deep and small holes.</abstract><cop>Wuhan</cop><pub>Wuhan University of Technology</pub><doi>10.1007/s11595-016-1345-4</doi><tpages>6</tpages></addata></record> |
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subjects | Chemistry and Materials Science Crosslinking Materials Science Mica Microcrystals Muscovite Orgamic Materials Photoinitiators Photopolymerization Sodium Swelling 亚甲基双丙烯酰胺 交联剂用量 合成 复合高吸水性树脂 对苯乙烯磺酸钠 微晶白云母 溶胀性能 紫外光聚合 |
title | Synthesis and Swelling Behaviors of Microcrystal Muscovite Composite Superabsorbent by Photopolymerization |
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