Improving the Photoluminescence Properties of Perovskite CH3NH3PbBr3-xClx Films by Modulating Organic Cation and Chlorine Concentrations

The photoluminescence (PL) properties of inorganic-organic perovskites can be drastically changed by tuning the halogen composition, especially the Cl content. However, our research demonstrated that in addition to the influence of Cl concentration, the PL emission intensity of CH3NH3PbBr3 strongly...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ACS applied materials & interfaces 2016-05, Vol.8 (20), p.12756-12763
Hauptverfasser: Yan, Jun, Zhang, Bing, Chen, Yunlin, Zhang, Ao, Ke, Xiaohan
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 12763
container_issue 20
container_start_page 12756
container_title ACS applied materials & interfaces
container_volume 8
creator Yan, Jun
Zhang, Bing
Chen, Yunlin
Zhang, Ao
Ke, Xiaohan
description The photoluminescence (PL) properties of inorganic-organic perovskites can be drastically changed by tuning the halogen composition, especially the Cl content. However, our research demonstrated that in addition to the influence of Cl concentration, the PL emission intensity of CH3NH3PbBr3 strongly depends on the content of CH3NH3Br in the coating solution. The effects of CH3NH3Br and Cl concentrations on the PL properties of CH3NH3PbBr3-xClx were investigated. We found that a strong PL emission intensity of CH3NH3PbBr3 can be obtained from solutions with a high CH3NH3Br concentration. The PL emission intensities of CH3NH3PbBr3-xClx films were enhanced by adjusting the molar ratio of PbBr to PbCl2 only in a highly concentrated CH3NH3Br environment. Moreover, it was found that an optimum CH3NH3Br/PbBr2/PbCl2 ratio in the precursor solutions can be used to obtain the strongest PL emission intensity of CH3NH3PbBr3-xClx films. Further studies revealed that both CH3NH3Br and Cl concentrations significantly influence the CH3NH3PbBr3-xClx films evolution, which affects their PL properties.
doi_str_mv 10.1021/acsami.6b01303
format Article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_1791737952</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1791737952</sourcerecordid><originalsourceid>FETCH-LOGICAL-p126t-939a73c3b2ed146bf57cd1db45090e31dfea159c57c6d041a6416a546f005f133</originalsourceid><addsrcrecordid>eNo1kL1OwzAURi0kREthZUQeWVL8EzvNCBGllQrtAHPkxE5rcOxgJ6h9Ax4bA2W6ut89OtJ3AbjCaIoRwbeiDqLVU14hTBE9AWOcp2kyI4yMwHkIbwhxShA7AyOSYU7pjI_B17LtvPvUdgv7nYKbneudGVptVaiVrWPiXad8r1WAroEbFeHwrnsFiwV9XtBNde9psi_MHs61aQOsDvDJycGI_se59lthdQ2LuDoLhZWw2Bnnox8WLvpt739P4QKcNsIEdXmcE_A6f3gpFslq_bgs7lZJhwnvk5zmIqM1rYiSOOVVw7JaYlmlDOVIUSwbJTDL6xhziVIseIq5YClvEGINpnQCbv68sfbHoEJftjpWNUZY5YZQ4izHGc1yRiJ6fUSHqlWy7LxuhT-U_9-j30_Tcc4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1791737952</pqid></control><display><type>article</type><title>Improving the Photoluminescence Properties of Perovskite CH3NH3PbBr3-xClx Films by Modulating Organic Cation and Chlorine Concentrations</title><source>ACS Publications</source><creator>Yan, Jun ; Zhang, Bing ; Chen, Yunlin ; Zhang, Ao ; Ke, Xiaohan</creator><creatorcontrib>Yan, Jun ; Zhang, Bing ; Chen, Yunlin ; Zhang, Ao ; Ke, Xiaohan</creatorcontrib><description>The photoluminescence (PL) properties of inorganic-organic perovskites can be drastically changed by tuning the halogen composition, especially the Cl content. However, our research demonstrated that in addition to the influence of Cl concentration, the PL emission intensity of CH3NH3PbBr3 strongly depends on the content of CH3NH3Br in the coating solution. The effects of CH3NH3Br and Cl concentrations on the PL properties of CH3NH3PbBr3-xClx were investigated. We found that a strong PL emission intensity of CH3NH3PbBr3 can be obtained from solutions with a high CH3NH3Br concentration. The PL emission intensities of CH3NH3PbBr3-xClx films were enhanced by adjusting the molar ratio of PbBr to PbCl2 only in a highly concentrated CH3NH3Br environment. Moreover, it was found that an optimum CH3NH3Br/PbBr2/PbCl2 ratio in the precursor solutions can be used to obtain the strongest PL emission intensity of CH3NH3PbBr3-xClx films. Further studies revealed that both CH3NH3Br and Cl concentrations significantly influence the CH3NH3PbBr3-xClx films evolution, which affects their PL properties.</description><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.6b01303</identifier><identifier>PMID: 27163386</identifier><language>eng</language><publisher>United States</publisher><ispartof>ACS applied materials &amp; interfaces, 2016-05, Vol.8 (20), p.12756-12763</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27163386$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yan, Jun</creatorcontrib><creatorcontrib>Zhang, Bing</creatorcontrib><creatorcontrib>Chen, Yunlin</creatorcontrib><creatorcontrib>Zhang, Ao</creatorcontrib><creatorcontrib>Ke, Xiaohan</creatorcontrib><title>Improving the Photoluminescence Properties of Perovskite CH3NH3PbBr3-xClx Films by Modulating Organic Cation and Chlorine Concentrations</title><title>ACS applied materials &amp; interfaces</title><addtitle>ACS Appl Mater Interfaces</addtitle><description>The photoluminescence (PL) properties of inorganic-organic perovskites can be drastically changed by tuning the halogen composition, especially the Cl content. However, our research demonstrated that in addition to the influence of Cl concentration, the PL emission intensity of CH3NH3PbBr3 strongly depends on the content of CH3NH3Br in the coating solution. The effects of CH3NH3Br and Cl concentrations on the PL properties of CH3NH3PbBr3-xClx were investigated. We found that a strong PL emission intensity of CH3NH3PbBr3 can be obtained from solutions with a high CH3NH3Br concentration. The PL emission intensities of CH3NH3PbBr3-xClx films were enhanced by adjusting the molar ratio of PbBr to PbCl2 only in a highly concentrated CH3NH3Br environment. Moreover, it was found that an optimum CH3NH3Br/PbBr2/PbCl2 ratio in the precursor solutions can be used to obtain the strongest PL emission intensity of CH3NH3PbBr3-xClx films. Further studies revealed that both CH3NH3Br and Cl concentrations significantly influence the CH3NH3PbBr3-xClx films evolution, which affects their PL properties.</description><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNo1kL1OwzAURi0kREthZUQeWVL8EzvNCBGllQrtAHPkxE5rcOxgJ6h9Ax4bA2W6ut89OtJ3AbjCaIoRwbeiDqLVU14hTBE9AWOcp2kyI4yMwHkIbwhxShA7AyOSYU7pjI_B17LtvPvUdgv7nYKbneudGVptVaiVrWPiXad8r1WAroEbFeHwrnsFiwV9XtBNde9psi_MHs61aQOsDvDJycGI_se59lthdQ2LuDoLhZWw2Bnnox8WLvpt739P4QKcNsIEdXmcE_A6f3gpFslq_bgs7lZJhwnvk5zmIqM1rYiSOOVVw7JaYlmlDOVIUSwbJTDL6xhziVIseIq5YClvEGINpnQCbv68sfbHoEJftjpWNUZY5YZQ4izHGc1yRiJ6fUSHqlWy7LxuhT-U_9-j30_Tcc4</recordid><startdate>20160525</startdate><enddate>20160525</enddate><creator>Yan, Jun</creator><creator>Zhang, Bing</creator><creator>Chen, Yunlin</creator><creator>Zhang, Ao</creator><creator>Ke, Xiaohan</creator><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20160525</creationdate><title>Improving the Photoluminescence Properties of Perovskite CH3NH3PbBr3-xClx Films by Modulating Organic Cation and Chlorine Concentrations</title><author>Yan, Jun ; Zhang, Bing ; Chen, Yunlin ; Zhang, Ao ; Ke, Xiaohan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p126t-939a73c3b2ed146bf57cd1db45090e31dfea159c57c6d041a6416a546f005f133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yan, Jun</creatorcontrib><creatorcontrib>Zhang, Bing</creatorcontrib><creatorcontrib>Chen, Yunlin</creatorcontrib><creatorcontrib>Zhang, Ao</creatorcontrib><creatorcontrib>Ke, Xiaohan</creatorcontrib><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>ACS applied materials &amp; interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yan, Jun</au><au>Zhang, Bing</au><au>Chen, Yunlin</au><au>Zhang, Ao</au><au>Ke, Xiaohan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improving the Photoluminescence Properties of Perovskite CH3NH3PbBr3-xClx Films by Modulating Organic Cation and Chlorine Concentrations</atitle><jtitle>ACS applied materials &amp; interfaces</jtitle><addtitle>ACS Appl Mater Interfaces</addtitle><date>2016-05-25</date><risdate>2016</risdate><volume>8</volume><issue>20</issue><spage>12756</spage><epage>12763</epage><pages>12756-12763</pages><eissn>1944-8252</eissn><abstract>The photoluminescence (PL) properties of inorganic-organic perovskites can be drastically changed by tuning the halogen composition, especially the Cl content. However, our research demonstrated that in addition to the influence of Cl concentration, the PL emission intensity of CH3NH3PbBr3 strongly depends on the content of CH3NH3Br in the coating solution. The effects of CH3NH3Br and Cl concentrations on the PL properties of CH3NH3PbBr3-xClx were investigated. We found that a strong PL emission intensity of CH3NH3PbBr3 can be obtained from solutions with a high CH3NH3Br concentration. The PL emission intensities of CH3NH3PbBr3-xClx films were enhanced by adjusting the molar ratio of PbBr to PbCl2 only in a highly concentrated CH3NH3Br environment. Moreover, it was found that an optimum CH3NH3Br/PbBr2/PbCl2 ratio in the precursor solutions can be used to obtain the strongest PL emission intensity of CH3NH3PbBr3-xClx films. Further studies revealed that both CH3NH3Br and Cl concentrations significantly influence the CH3NH3PbBr3-xClx films evolution, which affects their PL properties.</abstract><cop>United States</cop><pmid>27163386</pmid><doi>10.1021/acsami.6b01303</doi><tpages>8</tpages></addata></record>
fulltext fulltext
identifier EISSN: 1944-8252
ispartof ACS applied materials & interfaces, 2016-05, Vol.8 (20), p.12756-12763
issn 1944-8252
language eng
recordid cdi_proquest_miscellaneous_1791737952
source ACS Publications
title Improving the Photoluminescence Properties of Perovskite CH3NH3PbBr3-xClx Films by Modulating Organic Cation and Chlorine Concentrations
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T15%3A43%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Improving%20the%20Photoluminescence%20Properties%20of%20Perovskite%20CH3NH3PbBr3-xClx%20Films%20by%20Modulating%20Organic%20Cation%20and%20Chlorine%20Concentrations&rft.jtitle=ACS%20applied%20materials%20&%20interfaces&rft.au=Yan,%20Jun&rft.date=2016-05-25&rft.volume=8&rft.issue=20&rft.spage=12756&rft.epage=12763&rft.pages=12756-12763&rft.eissn=1944-8252&rft_id=info:doi/10.1021/acsami.6b01303&rft_dat=%3Cproquest_pubme%3E1791737952%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1791737952&rft_id=info:pmid/27163386&rfr_iscdi=true