Two Spin-State Reactivity in the Activation and Cleavage of CO2 by [ReO2]

The rhenium dioxide anion [ReO2] – reacts with carbon dioxide in a linear ion trap mass spectrometer to produce [ReO3] – corresponding to activation and cleavage of a C–O bond. Isotope labeling experiments using [Re18O2] – reveal that 18O/16O scrambling does not occur prior to cleavage of the C–O bo...

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Veröffentlicht in:	The journal of physical chemistry letters 2016-05, Vol.7 (10), p.1934-1938
Hauptverfasser:	Canale, Valentino, Robinson, Robert, Zavras, Athanasios, Khairallah, George N, d’Alessandro, Nicola, Yates, Brian F, O’Hair, Richard A. J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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