Copolymerization of Epichlorohydrin and CO2 Using Zinc Glutarate: An Additional Application of ZnGA in Polycarbonate Synthesis

The use of zinc glutarate (ZnGA) as a heterogeneous catalyst for the copolymerization of epichlorohydrin, an epoxide with an electron‐withdrawing substituent, and CO2 is reported. This catalyst shows the highest selectivity (98%) for polycarbonate over the cyclic carbonate in epichlorohydrin/CO2 cop...

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Veröffentlicht in:	Macromolecular rapid communications. 2016-05, Vol.37 (9), p.788-793
Hauptverfasser:	Sudakar, Padmanaban, Sivanesan, Dharmalingam, Yoon, Sungho
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Carbon Dioxide - chemistry Carbon monoxide Catalysts Chemical synthesis Copolymerization Epichlorohydrin Epichlorohydrin - chemistry Glass transition temperature Glutarates - chemistry heterogeneous catalysis Polycarbonate Polycarboxylate Cement - chemical synthesis Polycarboxylate Cement - chemistry Selectivity Temperature effects Zinc Zinc - chemistry zinc glutarate
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