New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory

A fifteen year contribution of computational studies carried out in close synergy with experiments is summarized. This interplay has allowed some important breakthroughs in the field of organolanthanide chemistry. The variety of different reaction mechanisms in lanthanide chemistry appear to be broa...

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Veröffentlicht in:Chemical Society reviews 2016-01, Vol.45 (9), p.2516-2543
Hauptverfasser: Kefalidis, Christos E, Castro, Ludovic, Perrin, Lionel, Rosal, Iker Del, Maron, Laurent
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container_issue 9
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container_title Chemical Society reviews
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creator Kefalidis, Christos E
Castro, Ludovic
Perrin, Lionel
Rosal, Iker Del
Maron, Laurent
description A fifteen year contribution of computational studies carried out in close synergy with experiments is summarized. This interplay has allowed some important breakthroughs in the field of organolanthanide chemistry. The variety of different reaction mechanisms in lanthanide chemistry appear to be broader than the simple bond metathesis. A fifteen year contribution of computational studies carried out in close synergy with experiments is summarized.
doi_str_mv 10.1039/c5cs00907c
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chemical Sciences
Computation
Decomposition reactions
Lanthanides
Metathesis
Reaction mechanisms
title New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory
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