Copper-mediated C(sp(3))-H azidation with Me3SiN3: synthesis of imidazoles from ketones and aldehydes
The efficient construction of 2,4,5-trisubstituted imidazoles, through a copper-mediated three-component reaction involving ketones, aldehydes, and Me3SiN3, has been developed. During the process, 4 C-N bonds were formed sequentially. Experimental results and DFT calculations suggested that azidatio...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-05, Vol.52 (38), p.6467-6470 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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