X-ray Absorption and Emission Spectroscopic Studies of [L2Fe2S2](n) Model Complexes: Implications for the Experimental Evaluation of Redox States in Iron-Sulfur Clusters

Herein, a systematic study of [L2Fe2S2](n) model complexes (where L = bis(benzimidazolato) and n = 2-, 3-, 4-) has been carried out using iron and sulfur K-edge X-ray absorption (XAS) and iron Kβ and valence-to-core X-ray emission spectroscopies (XES). These data are used as a test set to evaluate t...

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Veröffentlicht in:	Inorganic chemistry 2016-05, Vol.55 (9), p.4485-4497
Hauptverfasser:	Kowalska, Joanna K, Hahn, Anselm W, Albers, Antonia, Schiewer, Christine E, Bjornsson, Ragnar, Lima, Frederico A, Meyer, Franc, DeBeer, Serena
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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