Characterization of nano-lead-doped active carbon and its application in lead-acid battery
In this paper, nano-lead-doped active carbon (nano-Pb/AC) composite with low hydrogen evolution current for lead-acid battery was prepared by ultrasonic-absorption and chemical-precipitate method. The nano-Pb/AC composite was characterized by SEM, EDS and TEM. The electrochemical characterizations a...
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| Veröffentlicht in: | Journal of power sources 2014-12, Vol.270, p.332-341 |
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| creator | Hong, Bo Jiang, Liangxing Xue, Haitao Liu, Fangyang Jia, Ming Li, Jie Liu, Yexiang |
| description | In this paper, nano-lead-doped active carbon (nano-Pb/AC) composite with low hydrogen evolution current for lead-acid battery was prepared by ultrasonic-absorption and chemical-precipitate method. The nano-Pb/AC composite was characterized by SEM, EDS and TEM. The electrochemical characterizations are performed by linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) in a three-electrode system. Since intermediate adsorption is the rate-determining step, the hydrogen evolution reaction (HER) is markedly inhibited as the intermediate adsorption impedance of nano-Pb/AC increased. Meanwhile, the working potential of nano-Pb/AC is widened to the whole potential region of Pb negative plate (from −1.36 V to −0.86 V vs. Hg/HgSO4) in lead-acid battery. In addition, nano-Pb can improve the interfacial compatibility between AC and Pb paste, accordingly relieve the symptoms of carbon floatation. Finally, 2.0 V single-cell flooded lead-acid batteries with 1.0 wt.% nano-Pb/AC or 1.0 wt.% AC addition in negative active materials are assembled. The cell performances test results show that the 3 h rate capacity, quick charging performance, high current discharging performance and cycling performance of nano-Pb/AC modified battery are all improved compared with regular lead-acid battery and AC modified lead-acid battery.
•We researched the bad influences of AC used in lead-acid battery.•Nano-Pb/AC inhibited HER through increasing the adsorption impedance of hydrogen.•Nano-Pb/AC could overcome the negative effects of AC in lead-acid battery.•Nano-Pb/AC in negative plate can improve the performances of lead-acid battery. |
| doi_str_mv | 10.1016/j.jpowsour.2014.07.145 |
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•We researched the bad influences of AC used in lead-acid battery.•Nano-Pb/AC inhibited HER through increasing the adsorption impedance of hydrogen.•Nano-Pb/AC could overcome the negative effects of AC in lead-acid battery.•Nano-Pb/AC in negative plate can improve the performances of lead-acid battery.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2014.07.145</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Activated carbon ; Alternating current ; Applied sciences ; Direct energy conversion and energy accumulation ; Doped active carbon ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrochemical impedance spectroscopy ; Exact sciences and technology ; Flotation ; Hydrogen evolution ; Lead acid batteries ; Lead-acid battery ; Lead–carbon battery ; Nanostructure ; UltraBattery ; Voltammetry</subject><ispartof>Journal of power sources, 2014-12, Vol.270, p.332-341</ispartof><rights>2014 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c408t-8449176f0e47dd895d7949fa56d97bef0de42eb838aac3c5497049d6510b095d3</citedby><cites>FETCH-LOGICAL-c408t-8449176f0e47dd895d7949fa56d97bef0de42eb838aac3c5497049d6510b095d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jpowsour.2014.07.145$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27911,27912,45982</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28756409$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hong, Bo</creatorcontrib><creatorcontrib>Jiang, Liangxing</creatorcontrib><creatorcontrib>Xue, Haitao</creatorcontrib><creatorcontrib>Liu, Fangyang</creatorcontrib><creatorcontrib>Jia, Ming</creatorcontrib><creatorcontrib>Li, Jie</creatorcontrib><creatorcontrib>Liu, Yexiang</creatorcontrib><title>Characterization of nano-lead-doped active carbon and its application in lead-acid battery</title><title>Journal of power sources</title><description>In this paper, nano-lead-doped active carbon (nano-Pb/AC) composite with low hydrogen evolution current for lead-acid battery was prepared by ultrasonic-absorption and chemical-precipitate method. The nano-Pb/AC composite was characterized by SEM, EDS and TEM. The electrochemical characterizations are performed by linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) in a three-electrode system. Since intermediate adsorption is the rate-determining step, the hydrogen evolution reaction (HER) is markedly inhibited as the intermediate adsorption impedance of nano-Pb/AC increased. Meanwhile, the working potential of nano-Pb/AC is widened to the whole potential region of Pb negative plate (from −1.36 V to −0.86 V vs. Hg/HgSO4) in lead-acid battery. In addition, nano-Pb can improve the interfacial compatibility between AC and Pb paste, accordingly relieve the symptoms of carbon floatation. Finally, 2.0 V single-cell flooded lead-acid batteries with 1.0 wt.% nano-Pb/AC or 1.0 wt.% AC addition in negative active materials are assembled. The cell performances test results show that the 3 h rate capacity, quick charging performance, high current discharging performance and cycling performance of nano-Pb/AC modified battery are all improved compared with regular lead-acid battery and AC modified lead-acid battery.
•We researched the bad influences of AC used in lead-acid battery.•Nano-Pb/AC inhibited HER through increasing the adsorption impedance of hydrogen.•Nano-Pb/AC could overcome the negative effects of AC in lead-acid battery.•Nano-Pb/AC in negative plate can improve the performances of lead-acid battery.</description><subject>Activated carbon</subject><subject>Alternating current</subject><subject>Applied sciences</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Doped active carbon</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Exact sciences and technology</subject><subject>Flotation</subject><subject>Hydrogen evolution</subject><subject>Lead acid batteries</subject><subject>Lead-acid battery</subject><subject>Lead–carbon battery</subject><subject>Nanostructure</subject><subject>UltraBattery</subject><subject>Voltammetry</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqNkE1v1DAQhi0EEkvbv1DlgtRLwjj-zK3VCihSJS5w4WJN7InwKo2DnS0qv75Ztu21Pc1hnved0cPYOYeGA9efds1uTn9L2uemBS4bMA2X6g3bcGtE3Rql3rINCGNrY5R4zz6UsgMAzg1s2K_tb8zoF8rxHy4xTVUaqgmnVI-EoQ5pplCt-3hHlcfcrwBOoYpLqXCex-iPoThV_3n0MVQ9Lmvf_Sl7N-BY6OxxnrCfXz7_2F7XN9-_ftte3dRegl1qK2XHjR6ApAnBdiqYTnYDKh0609MAgWRLvRUW0QuvZGdAdkErDj2stDhhF8feOac_eyqLu43F0zjiRGlfHDdWt60WunsFqluhTCtgRfUR9TmVkmlwc463mO8dB3fw7nbuybs7eHdg3Op9DX58vIHF4zhknHwsz-nWGqUlHH65PHK0urmLlF3xkSZPIWbyiwspvnTqAUcNnK8</recordid><startdate>20141215</startdate><enddate>20141215</enddate><creator>Hong, Bo</creator><creator>Jiang, Liangxing</creator><creator>Xue, Haitao</creator><creator>Liu, Fangyang</creator><creator>Jia, Ming</creator><creator>Li, Jie</creator><creator>Liu, Yexiang</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7SP</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20141215</creationdate><title>Characterization of nano-lead-doped active carbon and its application in lead-acid battery</title><author>Hong, Bo ; Jiang, Liangxing ; Xue, Haitao ; Liu, Fangyang ; Jia, Ming ; Li, Jie ; Liu, Yexiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-8449176f0e47dd895d7949fa56d97bef0de42eb838aac3c5497049d6510b095d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Activated carbon</topic><topic>Alternating current</topic><topic>Applied sciences</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Doped active carbon</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Exact sciences and technology</topic><topic>Flotation</topic><topic>Hydrogen evolution</topic><topic>Lead acid batteries</topic><topic>Lead-acid battery</topic><topic>Lead–carbon battery</topic><topic>Nanostructure</topic><topic>UltraBattery</topic><topic>Voltammetry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hong, Bo</creatorcontrib><creatorcontrib>Jiang, Liangxing</creatorcontrib><creatorcontrib>Xue, Haitao</creatorcontrib><creatorcontrib>Liu, Fangyang</creatorcontrib><creatorcontrib>Jia, Ming</creatorcontrib><creatorcontrib>Li, Jie</creatorcontrib><creatorcontrib>Liu, Yexiang</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hong, Bo</au><au>Jiang, Liangxing</au><au>Xue, Haitao</au><au>Liu, Fangyang</au><au>Jia, Ming</au><au>Li, Jie</au><au>Liu, Yexiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of nano-lead-doped active carbon and its application in lead-acid battery</atitle><jtitle>Journal of power sources</jtitle><date>2014-12-15</date><risdate>2014</risdate><volume>270</volume><spage>332</spage><epage>341</epage><pages>332-341</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>In this paper, nano-lead-doped active carbon (nano-Pb/AC) composite with low hydrogen evolution current for lead-acid battery was prepared by ultrasonic-absorption and chemical-precipitate method. The nano-Pb/AC composite was characterized by SEM, EDS and TEM. The electrochemical characterizations are performed by linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) in a three-electrode system. Since intermediate adsorption is the rate-determining step, the hydrogen evolution reaction (HER) is markedly inhibited as the intermediate adsorption impedance of nano-Pb/AC increased. Meanwhile, the working potential of nano-Pb/AC is widened to the whole potential region of Pb negative plate (from −1.36 V to −0.86 V vs. Hg/HgSO4) in lead-acid battery. In addition, nano-Pb can improve the interfacial compatibility between AC and Pb paste, accordingly relieve the symptoms of carbon floatation. Finally, 2.0 V single-cell flooded lead-acid batteries with 1.0 wt.% nano-Pb/AC or 1.0 wt.% AC addition in negative active materials are assembled. The cell performances test results show that the 3 h rate capacity, quick charging performance, high current discharging performance and cycling performance of nano-Pb/AC modified battery are all improved compared with regular lead-acid battery and AC modified lead-acid battery.
•We researched the bad influences of AC used in lead-acid battery.•Nano-Pb/AC inhibited HER through increasing the adsorption impedance of hydrogen.•Nano-Pb/AC could overcome the negative effects of AC in lead-acid battery.•Nano-Pb/AC in negative plate can improve the performances of lead-acid battery.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2014.07.145</doi><tpages>10</tpages></addata></record> |
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| subjects | Activated carbon Alternating current Applied sciences Direct energy conversion and energy accumulation Doped active carbon Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrochemical impedance spectroscopy Exact sciences and technology Flotation Hydrogen evolution Lead acid batteries Lead-acid battery Lead–carbon battery Nanostructure UltraBattery Voltammetry |
| title | Characterization of nano-lead-doped active carbon and its application in lead-acid battery |
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