Beyond post-synthesis modification: evolution of metal-organic frameworks viabuilding block replacement

Metal-organic frameworks (MOFs) are hybrid porous materials with many potential applications, which intimately depend on the presence of chemical functionality either at the organic linkers and/or at the metal nodes. Functionality that cannot be introduced into MOFs directly via de novosyntheses can...

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Veröffentlicht in:Chemical Society reviews 2014-07, Vol.43 (16), p.5896-5912
Hauptverfasser: Deria, Pravas, Mondloch, Joseph E, Karagiaridi, Olga, Bury, Wojciech, Hupp, Joseph T, Farha, Omar K
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container_issue 16
container_start_page 5896
container_title Chemical Society reviews
container_volume 43
creator Deria, Pravas
Mondloch, Joseph E
Karagiaridi, Olga
Bury, Wojciech
Hupp, Joseph T
Farha, Omar K
description Metal-organic frameworks (MOFs) are hybrid porous materials with many potential applications, which intimately depend on the presence of chemical functionality either at the organic linkers and/or at the metal nodes. Functionality that cannot be introduced into MOFs directly via de novosyntheses can be accessed through post-synthesis modification (PSM) on the reactive moieties of the linkers and/or nodes without disrupting the metal-linker bonds. Even more intriguing methods that go beyond PSM are herein termed building block replacement(BBR) which encompasses (i) solvent-assisted linker exchange (SALE), (ii) non-bridging ligand replacement, and (iii) transmetalation. These one-step or tandem BBR processes involve exchanging key structural components of the MOF, which in turn should allow for the evolution of protoMOF structures (i.e., the utilization of a parent MOF as a template) to design MOFs composed of completely new components, presumably viasingle crystal to single crystal transformations. The influence of building block replacement on the stability and properties of MOFs will be discussed, and some insights into their mechanistic aspects are provided. Future perspectives providing a glimpse into how these techniques can lead to various unexplored areas of MOF chemistry are also presented.
doi_str_mv 10.1039/c4cs00067f
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Blocking
Crystal structure
Evolution
Exchange
Ligands
Metal-organic frameworks
Metalorganic compounds
Porous materials
Transformations
title Beyond post-synthesis modification: evolution of metal-organic frameworks viabuilding block replacement
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