On the Role of Chalcogen Donor Atoms in Diimine-Dichalcogenolate Pt super(II) SONLO Chromophores: Is It Worth Replacing Sulfur with Selenium?

Two new diimine-diselenolate Pt super(II) chromophores [Pt(bipy)(Me-dset)] (1) and [Pt(phen)(Me-dset)] (2) (Me-dset super(2-) = N-methyl-2-thioxothiazoline-4,5-diselenolate) were synthesized and characterized. The effect of replacing sulfur with selenium was investigated by comparing the UV/Vis spec...

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Veröffentlicht in:	European journal of inorganic chemistry 2015-11, Vol.2015 (31), p.5163-5170
Hauptverfasser:	Pintus, Anna, Aragoni, MCarla, Isaia, Francesco, Lippolis, Vito, Lorcy, Dominique, Slawin, Alexandra MZ, Woollins, JDerek, Arca, Massimiliano
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic beam spectroscopy Chromophores Neural networks Nonlinearity Optical properties Selenium Spectroscopy Sulfur
Online-Zugang:	Volltext
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