Identifying the role of terahertz vibrations in metal-organic frameworks: from gate-opening phenomenon to shear-driven structural destabilization

We present an unambiguous identification of low-frequency terahertz vibrations in the archetypal imidazole-based metal-organic framework (MOF) materials: ZIF-4, ZIF-7, and ZIF-8, all of which adopt a zeolite-like nanoporous structure. Using inelastic neutron scattering and synchrotron radiation far-...

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Veröffentlicht in:	Physical review letters 2014-11, Vol.113 (21), p.215502-215502, Article 215502
Hauptverfasser:	Ryder, Matthew R, Civalleri, Bartolomeo, Bennett, Thomas D, Henke, Sebastian, Rudić, Svemir, Cinque, Gianfelice, Fernandez-Alonso, Felix, Tan, Jin-Chong
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectroscopy Density functional theory Mathematical analysis Metal-organic frameworks Metalorganic compounds Nanostructure Neutron scattering Synchrotron radiation Vibration
Online-Zugang:	Volltext
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