Efficient Rhodium-Catalyzed Multicomponent Reaction for the Synthesis of Novel Propargylamines

[{Rh(μ‐Cl)(H)2(IPr)}2] (IPr = 1,3‐bis‐(2,6‐diisopropylphenyl)imidazole‐2‐ylidene) was found to be an efficient catalyst for the synthesis of novel propargylamines by a one‐pot three‐component reaction between primary arylamines, aliphatic aldehydes, and triisopropylsilylacetylene. This methodology o...

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Veröffentlicht in:	Chemistry : a European journal 2015-12, Vol.21 (49), p.17701-17707
Hauptverfasser:	Rubio-Pérez, Laura, Iglesias, Manuel, Munárriz, Julen, Polo, Victor, Pérez-Torrente, Jesús J., Oro, Luis A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Aliphatic compounds Amines Catalysis Catalysts Chemistry CH activation hydroalkynylation Mathematical analysis multicomponent reactions Organic compounds propargylamines rhodium Synthesis (chemistry)
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