Enantiopure Laterally Functionalized Alleno-Acetylenic Macrocycles: Synthesis, Chiroptical Properties, and Self-Assembly in Aqueous Media

A family of shape‐persistent alleno–acetylenic macrocycles (SPAAMs), peripherally decorated with structurally diverse pendant groups, has been synthesized and characterized in enantiomerically pure form. Their electronic circular dichroism (ECD) spectra feature a strong chiroptical response, which i...

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Veröffentlicht in:	Chemistry : a European journal 2014-12, Vol.20 (49), p.16070-16073
Hauptverfasser:	Tzirakis, Manolis D., Alberti, Mariza N., Weissman, Haim, Rybtchinski, Boris, Diederich, François
Format:	Artikel
Sprache:	eng
Schlagworte:	alleno-acetylenes Aqueous solutions Chemistry chiral macrocycles Circularity Decoration Dichroism electronic circular dichroism Electronics Fine structure Jewelry Macrocyclic compounds scanning probe microscopy Self assembly Spectra
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