Enzyme-directed pH-responsive exfoliation and dispersion of graphene and its decoration by gold nanoparticles for use as a hybrid catalyst

A non-destructive, safe and practical strategy to produce high quality graphene in high yield is urgently required, since this would pave the way for a wide range of applications of graphene in the future. Here we present a pH-responsive water-dispersible method for the exfoliation and functionaliza...

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Veröffentlicht in:Nano research 2013-09, Vol.6 (9), p.693-702
Hauptverfasser: Qu, Konggang, Wu, Li, Ren, Jinsong, Qu, Xiaogang
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creator Qu, Konggang
Wu, Li
Ren, Jinsong
Qu, Xiaogang
description A non-destructive, safe and practical strategy to produce high quality graphene in high yield is urgently required, since this would pave the way for a wide range of applications of graphene in the future. Here we present a pH-responsive water-dispersible method for the exfoliation and functionalization of graphene by using lysozyme. The pH-responsive dispersion of graphene may be useful for the reversible assembly of multicomponent/multifunctional nanohybrid materials and nanoscale electronic devices. More importantly, composites can be easily constructed through the interactions between disulphide groups in lysozyme and gold nanoparticles (AuNPs). The resulting graphene-AuNPs composites show excellent catalytic activity towards reduction of o-nitroaniline by NaBH4. Since lysozyme is low cost and has antibacterial properties, and has been widely used in food preservation, medicine and the pharmaceutical industry, our approach may open a new scalable route for the manufacture of high-quality, nondestructive graphene for practical applications.
doi_str_mv 10.1007/s12274-013-0345-3
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identifier ISSN: 1998-0124
ispartof Nano research, 2013-09, Vol.6 (9), p.693-702
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source Springer Online Journals - JUSTICE
subjects Aqueous solutions
Atomic/Molecular Structure and Spectra
Biomedicine
Biotechnology
Chemistry and Materials Science
Condensed Matter Physics
Dispersions
Electron microscopes
Enzymes
Exfoliation
Food preservation
Gold
Graphene
Graphite
Lysozyme
Materials Science
Microscopy
Nanocomposites
Nanomaterials
Nanoparticles
Nanostructure
Nanotechnology
Oxidation
Pharmaceutical industry
pH响应性
Proteins
Research Article
催化剂
分散体
溶菌酶
石墨
装饰用
金纳米粒子
金纳米颗粒
title Enzyme-directed pH-responsive exfoliation and dispersion of graphene and its decoration by gold nanoparticles for use as a hybrid catalyst
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