Alkyl Halide-Free Heteroatom Alkylation and Epoxidation Facilitated by a Recyclable Polymer-Supported Oxidant for the In-Flow Preparation of Diazo Compounds

Highly reactive metal carbenes, generated from simple ketones via diazo compounds, including diazo‐amides and ‐phosphonates, using a recyclable reagent in‐flow, are transient but versatile electrophiles for heteroatom alkylation reactions and for epoxide formation. The method produces no organic was...

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