Efficient Biomimetic Hydroxylation Catalysis with a Bis(pyrazolyl)imidazolylmethane Copper Peroxide Complex

Bis(pyrazolyl)methane ligands are excellent components of model complexes used to investigate the activity of the enzyme tyrosinase. Combining the N donors 3‐tert‐butylpyrazole and 1‐methylimidazole results in a ligand that is capable of stabilising a (μ‐η2:η2)‐dicopper(II) core that resembles the a...

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Veröffentlicht in:	Chemistry : a European journal 2015-12, Vol.21 (49), p.17639-17649
Hauptverfasser:	Wilfer, Claudia, Liebhäuser, Patricia, Hoffmann, Alexander, Erdmann, Hannes, Grossmann, Oleg, Runtsch, Leander, Paffenholz, Eva, Schepper, Rahel, Dick, Regina, Bauer, Matthias, Dürr, Maximilian, Ivanović-Burmazović, Ivana, Herres-Pawlis, Sonja
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological Phenomena biomimetic synthesis Biomimetics Catalysis Catalysts Chemistry Coordination compounds copper Copper - chemistry Hydroxylation Imidazoles - chemistry Kinetics Ligands Mathematical models Molecular Structure Monophenol Monooxygenase - chemistry Monophenol Monooxygenase - metabolism N ligands Oxyquinoline - chemistry Peroxides Photoelectron Spectroscopy Pyrazoles - chemistry structure-activity relationships Tyrosinase
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