Improved surface morphology of ultrananocrystalline diamond film by deaggregation of nanodiamond seeds

A significant improvement in surface morphology of ultrananocrystalline diamond (UNCD) film was achieved with hydrogen heat treatment of nanodiamond (ND) seed particles. By hydrogen heat treatment, the average size of ND aggregates was greatly reduced from ∼2 µm to ∼55 nm as the ND surfaces were mod...

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Veröffentlicht in:Physica status solidi. A, Applications and materials science Applications and materials science, 2014-08, Vol.211 (8), p.1782-1786
Hauptverfasser: Park, Jong Cheon, Jeong, Ok Geun, Son, Bit Na, Kim, Tae Gyu, Kim, Jin Kon, Ryu, Jeong Ho, Hwang, Sungu, Cho, Hyun
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container_end_page 1786
container_issue 8
container_start_page 1782
container_title Physica status solidi. A, Applications and materials science
container_volume 211
creator Park, Jong Cheon
Jeong, Ok Geun
Son, Bit Na
Kim, Tae Gyu
Kim, Jin Kon
Ryu, Jeong Ho
Hwang, Sungu
Cho, Hyun
description A significant improvement in surface morphology of ultrananocrystalline diamond (UNCD) film was achieved with hydrogen heat treatment of nanodiamond (ND) seed particles. By hydrogen heat treatment, the average size of ND aggregates was greatly reduced from ∼2 µm to ∼55 nm as the ND surfaces were modified to hydrogen‐containing functionalities. Si surfaces seeded with the hydrogen heat‐treated ND seeds showed very high seeds densities up to ∼1011 cm−2. The grown UNCD film with ND seeds treated at 600 °C provided a very smooth surface morphology consisted of small and uniformly distributed grains compared to the film grown with untreated ND seeds. AFM scan image of the grown UNCD films seeded with untreated and hydrogen heat‐treated ND particles.
doi_str_mv 10.1002/pssa.201330557
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By hydrogen heat treatment, the average size of ND aggregates was greatly reduced from ∼2 µm to ∼55 nm as the ND surfaces were modified to hydrogen‐containing functionalities. Si surfaces seeded with the hydrogen heat‐treated ND seeds showed very high seeds densities up to ∼1011 cm−2. The grown UNCD film with ND seeds treated at 600 °C provided a very smooth surface morphology consisted of small and uniformly distributed grains compared to the film grown with untreated ND seeds. 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source Wiley Online Library Journals Frontfile Complete
subjects Aggregates
deaggregation
Density
Diamonds
Heat treatment
heat treatments
Hydrogen
Morphology
Nanostructure
Seeds
surface morphology
ultrananocrystalline diamond
title Improved surface morphology of ultrananocrystalline diamond film by deaggregation of nanodiamond seeds
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