Taming Hazardous Chemistry in Flow: The Continuous Processing of Diazo and Diazonium Compounds
The synthetic utilities of the diazo and diazonium groups are matched only by their reputation for explosive decomposition. Continuous processing technology offers new opportunities to make and use these versatile intermediates at a range of scales with improved safety over traditional batch process...
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| Veröffentlicht in: | Chemistry : a European journal 2015-02, Vol.21 (6), p.2298-2308 |
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| container_end_page | 2308 |
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| container_issue | 6 |
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| container_title | Chemistry : a European journal |
| container_volume | 21 |
| creator | Deadman, Benjamin J. Collins, Stuart G. Maguire, Anita R. |
| description | The synthetic utilities of the diazo and diazonium groups are matched only by their reputation for explosive decomposition. Continuous processing technology offers new opportunities to make and use these versatile intermediates at a range of scales with improved safety over traditional batch processes. In this minireview, the state of the art in the continuous flow processing of reactive diazo and diazonium species is discussed.
Safety first: The synthetic utilities of the diazo and diazonium groups are matched only by their reputation for explosive decomposition. Continuous processing technology offers new opportunities to make and use these versatile intermediates with improved safety. This Minireview discusses the state of the art in flow chemistry involving these reactive species. |
| doi_str_mv | 10.1002/chem.201404348 |
| format | Article |
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Safety first: The synthetic utilities of the diazo and diazonium groups are matched only by their reputation for explosive decomposition. Continuous processing technology offers new opportunities to make and use these versatile intermediates with improved safety. 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| ispartof | Chemistry : a European journal, 2015-02, Vol.21 (6), p.2298-2308 |
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| language | eng |
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| source | MEDLINE; Wiley Journals |
| subjects | Batch processes Catalysis Chemistry Continuous flow Continuous processing Decomposition diazocarbonyls diazomethane Diazomethane - chemical synthesis Diazomethane - chemistry Diazonium Compounds - chemical synthesis Diazonium Compounds - chemistry diazonium ions Explosions flow chemistry Hazardous Rhodium - chemistry Safety State of the art Utilities |
| title | Taming Hazardous Chemistry in Flow: The Continuous Processing of Diazo and Diazonium Compounds |
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