Hollow PAQR nanostructure and its smart electrorheological activity

Hollow polyacene quinone radical (PAQR) submicrospheres are synthesized by a modified solvothermal method. The morphology and structure of the hollow PAQR submicrospheres were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD)...

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Veröffentlicht in:Polymer (Guilford) 2016-01, Vol.83, p.129-137
Hauptverfasser: Wang, Baoxiang, Tian, Xiaoli, He, Kai, Ma, Lili, Yu, Shoushan, Hao, Chuncheng, Chen, Kezheng, Lei, Qingquan
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container_end_page 137
container_issue
container_start_page 129
container_title Polymer (Guilford)
container_volume 83
creator Wang, Baoxiang
Tian, Xiaoli
He, Kai
Ma, Lili
Yu, Shoushan
Hao, Chuncheng
Chen, Kezheng
Lei, Qingquan
description Hollow polyacene quinone radical (PAQR) submicrospheres are synthesized by a modified solvothermal method. The morphology and structure of the hollow PAQR submicrospheres were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD) and Haake rotational rheometer, respectively. Meanwhile, both the size and the shell thickness of PAQR hollow submicrospheres could be adjusted by changing the amount of surfactant-sodium dodecyl sulfate (SDS). When PAQR hollow submicrospheres are used as the electrorheological (ER) dispersed materials, good ER effect is achieved. Furthermore, the hollow structure is beneficial to improve the anti-sedimentation property for ER application. Hollow PAQR submicrospheres with controllable sizes and shell thicknesses are easily synthesized by the solvothermal method, which can be used as a smart electrorheological materials. [Display omitted] •Hollow polyacene quinone radical (PAQR) submicrospheres are synthesized by a modified solvothermal method.•Both the size and the shell thickness of PAQR hollow submicrospheres could be adjusted by changing the amount of SDS.•Hollow PAQR polymers exhibit smart electrorheological behaviour.
doi_str_mv 10.1016/j.polymer.2015.12.004
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The morphology and structure of the hollow PAQR submicrospheres were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD) and Haake rotational rheometer, respectively. Meanwhile, both the size and the shell thickness of PAQR hollow submicrospheres could be adjusted by changing the amount of surfactant-sodium dodecyl sulfate (SDS). When PAQR hollow submicrospheres are used as the electrorheological (ER) dispersed materials, good ER effect is achieved. Furthermore, the hollow structure is beneficial to improve the anti-sedimentation property for ER application. Hollow PAQR submicrospheres with controllable sizes and shell thicknesses are easily synthesized by the solvothermal method, which can be used as a smart electrorheological materials. 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subjects Conductive polymer
Diffraction
Electrorheological fluid
Hollow nanostructures
PAQR
Quinones
Radicals
Rotational
Scanning electron microscopy
Soft template
Solvothermal method
Transmission electron microscopy
X-ray diffraction
X-rays
title Hollow PAQR nanostructure and its smart electrorheological activity
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