Recent developments of thiacalixarene based molecular motifs
Thiacalixarenes, a subclass of " third generation " calixarenes, exhibit many interesting features such as enlarged ring size, facile chemical modification, and metal complexation due to the presence of bridging sulfur atoms. The thiacalixarene scaffold is a unique host with vast possibili...
Gespeichert in:
| Veröffentlicht in: | Chemical Society reviews 2014-07, Vol.43 (13), p.4824-487 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 487 |
|---|---|
| container_issue | 13 |
| container_start_page | 4824 |
| container_title | Chemical Society reviews |
| container_volume | 43 |
| creator | Kumar, Rajesh Lee, Yeon Ok Bhalla, Vandana Kumar, Manoj Kim, Jong Seung |
| description | Thiacalixarenes, a subclass of "
third generation
" calixarenes, exhibit many interesting features such as enlarged ring size, facile chemical modification, and metal complexation due to the presence of bridging sulfur atoms. The thiacalixarene scaffold is a unique host with vast possibilities for functionalization not only at the upper and lower rim but also at the bridging sulfide groups. Modified thiacalixarenes have been used for many applications such as the detection and separation of biologically important cations, anions, and bio-analytes, mimicking molecular logic gates and devices, and synthesis of self-assembled coordination cages, multinuclear complexes, magnetic materials and luminescent materials. This review article summarizes recent developments in the derivatization methods of thiacalixarenes and their utilization in various applications.
This review article summarizes recent developments in the derivatization methods of thiacalixarenes and their utilization in various applications. |
| doi_str_mv | 10.1039/c4cs00068d |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1786176835</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1534792878</sourcerecordid><originalsourceid>FETCH-LOGICAL-c368t-ee0c440fd0bc24deedf6675d5b72a92be60e61864f032df05eb1897403dbe3ea3</originalsourceid><addsrcrecordid>eNqFkEtLxDAUhYMozji6ca_UnQjVm0eTFNzI4AsGBNF1SZMbrLTTmrSi_97KjIobXd0PzseBewjZp3BKgednVtgIAFK7DTKlQkIqlBCbZAocZApA2YTsxPg8ElWSbZMJE1JTKdmUnN-jxWWfOHzFuu2akWPS-qR_qow1dfVmAi4xKU1ElzRtjXaoTRipr3zcJVve1BH31ndGHq8uH-Y36eLu-nZ-sUgtl7pPEcEKAd5BaZlwiM5LqTKXlYqZnJUoASXVUnjgzHnIsKQ6VwK4K5Gj4TNyvOrtQvsyYOyLpooW69ossR1iQZWW42eaZ_-rGRcqZ1rpUT1ZqTa0MQb0RReqxoT3gkLxOWzxM-woH657h7JB961-LTkKByshRPud_io4-isvOuf5B1wxiMk</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1534792878</pqid></control><display><type>article</type><title>Recent developments of thiacalixarene based molecular motifs</title><source>MEDLINE</source><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Kumar, Rajesh ; Lee, Yeon Ok ; Bhalla, Vandana ; Kumar, Manoj ; Kim, Jong Seung</creator><creatorcontrib>Kumar, Rajesh ; Lee, Yeon Ok ; Bhalla, Vandana ; Kumar, Manoj ; Kim, Jong Seung</creatorcontrib><description>Thiacalixarenes, a subclass of "
third generation
" calixarenes, exhibit many interesting features such as enlarged ring size, facile chemical modification, and metal complexation due to the presence of bridging sulfur atoms. The thiacalixarene scaffold is a unique host with vast possibilities for functionalization not only at the upper and lower rim but also at the bridging sulfide groups. Modified thiacalixarenes have been used for many applications such as the detection and separation of biologically important cations, anions, and bio-analytes, mimicking molecular logic gates and devices, and synthesis of self-assembled coordination cages, multinuclear complexes, magnetic materials and luminescent materials. This review article summarizes recent developments in the derivatization methods of thiacalixarenes and their utilization in various applications.
This review article summarizes recent developments in the derivatization methods of thiacalixarenes and their utilization in various applications.</description><identifier>ISSN: 0306-0012</identifier><identifier>EISSN: 1460-4744</identifier><identifier>DOI: 10.1039/c4cs00068d</identifier><identifier>PMID: 24681662</identifier><language>eng</language><publisher>England</publisher><subject>Bridging ; Cages ; Calixarenes - chemistry ; Cations ; Complexation ; Devices ; Expansion ; Models, Molecular ; Sulfides ; Utilization</subject><ispartof>Chemical Society reviews, 2014-07, Vol.43 (13), p.4824-487</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-ee0c440fd0bc24deedf6675d5b72a92be60e61864f032df05eb1897403dbe3ea3</citedby><cites>FETCH-LOGICAL-c368t-ee0c440fd0bc24deedf6675d5b72a92be60e61864f032df05eb1897403dbe3ea3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24681662$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kumar, Rajesh</creatorcontrib><creatorcontrib>Lee, Yeon Ok</creatorcontrib><creatorcontrib>Bhalla, Vandana</creatorcontrib><creatorcontrib>Kumar, Manoj</creatorcontrib><creatorcontrib>Kim, Jong Seung</creatorcontrib><title>Recent developments of thiacalixarene based molecular motifs</title><title>Chemical Society reviews</title><addtitle>Chem Soc Rev</addtitle><description>Thiacalixarenes, a subclass of "
third generation
" calixarenes, exhibit many interesting features such as enlarged ring size, facile chemical modification, and metal complexation due to the presence of bridging sulfur atoms. The thiacalixarene scaffold is a unique host with vast possibilities for functionalization not only at the upper and lower rim but also at the bridging sulfide groups. Modified thiacalixarenes have been used for many applications such as the detection and separation of biologically important cations, anions, and bio-analytes, mimicking molecular logic gates and devices, and synthesis of self-assembled coordination cages, multinuclear complexes, magnetic materials and luminescent materials. This review article summarizes recent developments in the derivatization methods of thiacalixarenes and their utilization in various applications.
This review article summarizes recent developments in the derivatization methods of thiacalixarenes and their utilization in various applications.</description><subject>Bridging</subject><subject>Cages</subject><subject>Calixarenes - chemistry</subject><subject>Cations</subject><subject>Complexation</subject><subject>Devices</subject><subject>Expansion</subject><subject>Models, Molecular</subject><subject>Sulfides</subject><subject>Utilization</subject><issn>0306-0012</issn><issn>1460-4744</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkEtLxDAUhYMozji6ca_UnQjVm0eTFNzI4AsGBNF1SZMbrLTTmrSi_97KjIobXd0PzseBewjZp3BKgednVtgIAFK7DTKlQkIqlBCbZAocZApA2YTsxPg8ElWSbZMJE1JTKdmUnN-jxWWfOHzFuu2akWPS-qR_qow1dfVmAi4xKU1ElzRtjXaoTRipr3zcJVve1BH31ndGHq8uH-Y36eLu-nZ-sUgtl7pPEcEKAd5BaZlwiM5LqTKXlYqZnJUoASXVUnjgzHnIsKQ6VwK4K5Gj4TNyvOrtQvsyYOyLpooW69ossR1iQZWW42eaZ_-rGRcqZ1rpUT1ZqTa0MQb0RReqxoT3gkLxOWzxM-woH657h7JB961-LTkKByshRPud_io4-isvOuf5B1wxiMk</recordid><startdate>20140707</startdate><enddate>20140707</enddate><creator>Kumar, Rajesh</creator><creator>Lee, Yeon Ok</creator><creator>Bhalla, Vandana</creator><creator>Kumar, Manoj</creator><creator>Kim, Jong Seung</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140707</creationdate><title>Recent developments of thiacalixarene based molecular motifs</title><author>Kumar, Rajesh ; Lee, Yeon Ok ; Bhalla, Vandana ; Kumar, Manoj ; Kim, Jong Seung</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-ee0c440fd0bc24deedf6675d5b72a92be60e61864f032df05eb1897403dbe3ea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Bridging</topic><topic>Cages</topic><topic>Calixarenes - chemistry</topic><topic>Cations</topic><topic>Complexation</topic><topic>Devices</topic><topic>Expansion</topic><topic>Models, Molecular</topic><topic>Sulfides</topic><topic>Utilization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kumar, Rajesh</creatorcontrib><creatorcontrib>Lee, Yeon Ok</creatorcontrib><creatorcontrib>Bhalla, Vandana</creatorcontrib><creatorcontrib>Kumar, Manoj</creatorcontrib><creatorcontrib>Kim, Jong Seung</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical Society reviews</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kumar, Rajesh</au><au>Lee, Yeon Ok</au><au>Bhalla, Vandana</au><au>Kumar, Manoj</au><au>Kim, Jong Seung</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent developments of thiacalixarene based molecular motifs</atitle><jtitle>Chemical Society reviews</jtitle><addtitle>Chem Soc Rev</addtitle><date>2014-07-07</date><risdate>2014</risdate><volume>43</volume><issue>13</issue><spage>4824</spage><epage>487</epage><pages>4824-487</pages><issn>0306-0012</issn><eissn>1460-4744</eissn><abstract>Thiacalixarenes, a subclass of "
third generation
" calixarenes, exhibit many interesting features such as enlarged ring size, facile chemical modification, and metal complexation due to the presence of bridging sulfur atoms. The thiacalixarene scaffold is a unique host with vast possibilities for functionalization not only at the upper and lower rim but also at the bridging sulfide groups. Modified thiacalixarenes have been used for many applications such as the detection and separation of biologically important cations, anions, and bio-analytes, mimicking molecular logic gates and devices, and synthesis of self-assembled coordination cages, multinuclear complexes, magnetic materials and luminescent materials. This review article summarizes recent developments in the derivatization methods of thiacalixarenes and their utilization in various applications.
This review article summarizes recent developments in the derivatization methods of thiacalixarenes and their utilization in various applications.</abstract><cop>England</cop><pmid>24681662</pmid><doi>10.1039/c4cs00068d</doi><tpages>47</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0306-0012 |
| ispartof | Chemical Society reviews, 2014-07, Vol.43 (13), p.4824-487 |
| issn | 0306-0012 1460-4744 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1786176835 |
| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Bridging Cages Calixarenes - chemistry Cations Complexation Devices Expansion Models, Molecular Sulfides Utilization |
| title | Recent developments of thiacalixarene based molecular motifs |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T23%3A00%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Recent%20developments%20of%20thiacalixarene%20based%20molecular%20motifs&rft.jtitle=Chemical%20Society%20reviews&rft.au=Kumar,%20Rajesh&rft.date=2014-07-07&rft.volume=43&rft.issue=13&rft.spage=4824&rft.epage=487&rft.pages=4824-487&rft.issn=0306-0012&rft.eissn=1460-4744&rft_id=info:doi/10.1039/c4cs00068d&rft_dat=%3Cproquest_cross%3E1534792878%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1534792878&rft_id=info:pmid/24681662&rfr_iscdi=true |