BrettPhos Ligand Supported Palladium-Catalyzed CO Bond Formation through an Electronic Pathway of Reductive Elimination: Fluoroalkoxylation of Activated Aryl Halides

We report an unprecedented BrettPhos ligand supported Pd‐catalyzed CO bond‐forming reaction of activated aryl halides with primary fluoroalkyl alcohols. We demonstrate that the Phosphine ligand (BrettPhos) possesses the property of altering the mechanistic pathway of reductive elimination from nucl...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2014-10, Vol.20 (44), p.14218-14225
Hauptverfasser:	Rangarajan, T. M., Singh, Rajendra, Brahma, Raju, Devi, Kavita, Singh, Rishi Pal, Singh, R. P., Prasad, Ashok K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Activated alcohols Aromatic compounds Bonding BrettPhos CO coupling ethers Halides Ligands Nucleophiles Palladium Pathways reductive elimination
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!