A Closer Look at Spontaneous Mirror Symmetry Breaking in Aldol Reactions

The aldol reaction between acetone and 4‐nitrobenzaldehyde run in the nominal absence of any enantioselective catalyst was monitored by chiral HPLC with the aid of an internal standard. The collected data show the presence of a detectable initial enantiomeric excess of the aldol product in the early...

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Veröffentlicht in:	Chemistry : a European journal 2014-12, Vol.20 (52), p.17395-17408
Hauptverfasser:	Valero, Guillem, Ribó, Josep M., Moyano, Albert
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetone Aldehydes aldol reaction Autocatalysis Benzaldehydes - chemistry biological homochirality Broken symmetry Catalysis Catalysts Chemical Phenomena Chemistry Chromatography, High Pressure Liquid Inhibition mirror symmetry breaking Models, Chemical Networks organocatalysis Spontaneous Stereoisomerism Symmetry Thermodynamics
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