Ethylene Oligomerization Using Bis(imino)pyridinecobalt(II) Complexes Immobilized in Fluorotetrasilicic Mica Interlayer as Heterogeneous Catalysts

Heterogeneous bis(imino)pyridinecobalt(II) catalysts were prepared by direct reaction of cobalt-ion-exchanged fluorotetrasilicic mica and a bis(imino)pyridine ligand. The catalyst prepared from the ligand with 2-CF3Ph groups on the imino nitrogen showed high activity in ethylene oligomerization, wit...

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Veröffentlicht in:	Chemistry letters 2014, Vol.43 (8), p.1365-1367
Hauptverfasser:	Kurokawa, Hideki, Ishikawa, Shun, Yamamoto, Kazuhiro, Sakuragi, Tsutomu, Ohshima, Masa-aki, Miura, Hiroshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Ethylene Interlayers Ligands Mica Oligomerization Selectivity
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container_title	Chemistry letters
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creator	Kurokawa, Hideki Ishikawa, Shun Yamamoto, Kazuhiro Sakuragi, Tsutomu Ohshima, Masa-aki Miura, Hiroshi
description	Heterogeneous bis(imino)pyridinecobalt(II) catalysts were prepared by direct reaction of cobalt-ion-exchanged fluorotetrasilicic mica and a bis(imino)pyridine ligand. The catalyst prepared from the ligand with 2-CF3Ph groups on the imino nitrogen showed high activity in ethylene oligomerization, with excellent selectivity for α-olefins.
doi_str_mv	10.1246/cl.140319
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Catalysis Catalysts Ethylene Interlayers Ligands Mica Oligomerization Selectivity
title	Ethylene Oligomerization Using Bis(imino)pyridinecobalt(II) Complexes Immobilized in Fluorotetrasilicic Mica Interlayer as Heterogeneous Catalysts
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