Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis

A simple and regiospecific aminohydroxylation of olefins by photoredox catalysis has been developed. N‐protected 1‐aminopyridinium salts are the key compounds and serve as amidyl radical precursors by the action of Ir photocatalysts, fac‐[Ir(ppy)3] and [Ir(ppy)2(dtbbpy)](PF6) (ppy=2‐pyridylphenyl, d...

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Veröffentlicht in:	Chemistry : a European journal 2015-08, Vol.21 (33), p.11677-11680
Hauptverfasser:	Miyazawa, Kazuki, Koike, Takashi, Akita, Munetaka
Format:	Artikel
Sprache:	eng
Schlagworte:	amination carbocations Catalysis Chemistry Derivatives electron transfer homogeneous catalysis Olefins Photocatalysis Photocatalysts photochemistry Precursors Radicals Synthesis
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