The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy
1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′)dithiophene-2,6...
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creator | Yao, En-Ping Chen, Chun-Chao Gao, Jing Liu, Yongsheng Chen, Qi Cai, Min Hsu, Wei-Chou Hong, Ziruo Li, Gang Yang, Yang |
description | 1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′)dithiophene-2,6-diyl-alt- (alkyl thieno(3,4-b) thiophene-2-carboxylate)-2,6-diyl) (PBDTTT-C):PC70BM in BHJ with DIO as additive. Based on our results, we were able to simulate the device into an equivalent circuit model, which allows us to conveniently analyze the organic/organic interfacial contact in the organic photovoltaic (OPV) device. Thus, we demonstrate that the impedance spectroscopy can an effective approach in characterizing the donor/acceptor interfaces, such that a direct correlation can be established between the morphology and the device performance of BHJ devices.
•BHJ of high efficient OPV with additive was analyzed via impedance spectroscopy.•The interface between donor/acceptor in BHJ layer was studied by simulated circuit.•Carrier lifetimes was calculated from simulated elements and correspond to OPV performance. |
doi_str_mv | 10.1016/j.solmat.2014.05.049 |
format | Article |
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•BHJ of high efficient OPV with additive was analyzed via impedance spectroscopy.•The interface between donor/acceptor in BHJ layer was studied by simulated circuit.•Carrier lifetimes was calculated from simulated elements and correspond to OPV performance.</description><identifier>ISSN: 0927-0248</identifier><identifier>EISSN: 1879-3398</identifier><identifier>DOI: 10.1016/j.solmat.2014.05.049</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Additives ; Applied sciences ; Bulk heterojuction ; Contact ; Devices ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Energy ; Exact sciences and technology ; Impedance spectroscopy ; Interface ; Morphology ; Natural energy ; OPV ; Photoelectric conversion ; Photovoltaic cells ; Photovoltaic conversion ; Solar cells ; Solar cells. Photoelectrochemical cells ; Solar energy</subject><ispartof>Solar energy materials and solar cells, 2014-11, Vol.130, p.20-26</ispartof><rights>2014</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c443t-5c235536f246a5b6f33a0d66596477a3f9956809e5364a45ff5f51ec04919c543</citedby><cites>FETCH-LOGICAL-c443t-5c235536f246a5b6f33a0d66596477a3f9956809e5364a45ff5f51ec04919c543</cites><orcidid>0000-0002-2853-2741 ; 0000-0003-2059-0290</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.solmat.2014.05.049$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,3550,23930,23931,25140,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28858410$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Yao, En-Ping</creatorcontrib><creatorcontrib>Chen, Chun-Chao</creatorcontrib><creatorcontrib>Gao, Jing</creatorcontrib><creatorcontrib>Liu, Yongsheng</creatorcontrib><creatorcontrib>Chen, Qi</creatorcontrib><creatorcontrib>Cai, Min</creatorcontrib><creatorcontrib>Hsu, Wei-Chou</creatorcontrib><creatorcontrib>Hong, Ziruo</creatorcontrib><creatorcontrib>Li, Gang</creatorcontrib><creatorcontrib>Yang, Yang</creatorcontrib><title>The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy</title><title>Solar energy materials and solar cells</title><description>1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′)dithiophene-2,6-diyl-alt- (alkyl thieno(3,4-b) thiophene-2-carboxylate)-2,6-diyl) (PBDTTT-C):PC70BM in BHJ with DIO as additive. Based on our results, we were able to simulate the device into an equivalent circuit model, which allows us to conveniently analyze the organic/organic interfacial contact in the organic photovoltaic (OPV) device. Thus, we demonstrate that the impedance spectroscopy can an effective approach in characterizing the donor/acceptor interfaces, such that a direct correlation can be established between the morphology and the device performance of BHJ devices.
•BHJ of high efficient OPV with additive was analyzed via impedance spectroscopy.•The interface between donor/acceptor in BHJ layer was studied by simulated circuit.•Carrier lifetimes was calculated from simulated elements and correspond to OPV performance.</description><subject>Additives</subject><subject>Applied sciences</subject><subject>Bulk heterojuction</subject><subject>Contact</subject><subject>Devices</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Impedance spectroscopy</subject><subject>Interface</subject><subject>Morphology</subject><subject>Natural energy</subject><subject>OPV</subject><subject>Photoelectric conversion</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>Solar cells</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><issn>0927-0248</issn><issn>1879-3398</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqNkMtKxDAUhoMoOF7ewEU2gpvWpLm02Qgi3kBwo-sQ0xPM0E5qkinM25sy4lJc5UC-_1w-hC4oqSmh8npdpzCMJtcNobwmoiZcHaAV7VpVMaa6Q7Qiqmkr0vDuGJ2ktCaENJLxFbJvn4BT3vY7HBwubWbYZGz63mc_AwbnwOaE_WYpvfXL7xSG3QgRT58hhzkM2Xib8OwN9uMEvdnY0nIquRiSDdPuDB05MyQ4_3lP0fvD_dvdU_Xy-vh8d_tSWc5ZroRtmBBMuoZLIz6kY8yQXkqhJG9bw5xSQnZEQWG44cI54QQFW46lygrOTtHVvu8Uw9cWUtajTxaGwWwgbJOmbSeplFzKf6CyLCNboQrK96gt56QITk_RjybuNCV60a_Xeq9fL_o1EbpsVGKXPxNMsmZwsWjx6TfbdJ3oOCWFu9lzUMzMHqJOi2ULvY9Foe6D_3vQN-51nYA</recordid><startdate>20141101</startdate><enddate>20141101</enddate><creator>Yao, En-Ping</creator><creator>Chen, Chun-Chao</creator><creator>Gao, Jing</creator><creator>Liu, Yongsheng</creator><creator>Chen, Qi</creator><creator>Cai, Min</creator><creator>Hsu, Wei-Chou</creator><creator>Hong, Ziruo</creator><creator>Li, Gang</creator><creator>Yang, Yang</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TG</scope><scope>KL.</scope><scope>7SP</scope><scope>7TB</scope><scope>7U5</scope><scope>8FD</scope><scope>FR3</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-2853-2741</orcidid><orcidid>https://orcid.org/0000-0003-2059-0290</orcidid></search><sort><creationdate>20141101</creationdate><title>The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy</title><author>Yao, En-Ping ; Chen, Chun-Chao ; Gao, Jing ; Liu, Yongsheng ; Chen, Qi ; Cai, Min ; Hsu, Wei-Chou ; Hong, Ziruo ; Li, Gang ; Yang, Yang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c443t-5c235536f246a5b6f33a0d66596477a3f9956809e5364a45ff5f51ec04919c543</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Additives</topic><topic>Applied sciences</topic><topic>Bulk heterojuction</topic><topic>Contact</topic><topic>Devices</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Impedance spectroscopy</topic><topic>Interface</topic><topic>Morphology</topic><topic>Natural energy</topic><topic>OPV</topic><topic>Photoelectric conversion</topic><topic>Photovoltaic cells</topic><topic>Photovoltaic conversion</topic><topic>Solar cells</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yao, En-Ping</creatorcontrib><creatorcontrib>Chen, Chun-Chao</creatorcontrib><creatorcontrib>Gao, Jing</creatorcontrib><creatorcontrib>Liu, Yongsheng</creatorcontrib><creatorcontrib>Chen, Qi</creatorcontrib><creatorcontrib>Cai, Min</creatorcontrib><creatorcontrib>Hsu, Wei-Chou</creatorcontrib><creatorcontrib>Hong, Ziruo</creatorcontrib><creatorcontrib>Li, Gang</creatorcontrib><creatorcontrib>Yang, Yang</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solar energy materials and solar cells</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yao, En-Ping</au><au>Chen, Chun-Chao</au><au>Gao, Jing</au><au>Liu, Yongsheng</au><au>Chen, Qi</au><au>Cai, Min</au><au>Hsu, Wei-Chou</au><au>Hong, Ziruo</au><au>Li, Gang</au><au>Yang, Yang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy</atitle><jtitle>Solar energy materials and solar cells</jtitle><date>2014-11-01</date><risdate>2014</risdate><volume>130</volume><spage>20</spage><epage>26</epage><pages>20-26</pages><issn>0927-0248</issn><eissn>1879-3398</eissn><abstract>1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′)dithiophene-2,6-diyl-alt- (alkyl thieno(3,4-b) thiophene-2-carboxylate)-2,6-diyl) (PBDTTT-C):PC70BM in BHJ with DIO as additive. Based on our results, we were able to simulate the device into an equivalent circuit model, which allows us to conveniently analyze the organic/organic interfacial contact in the organic photovoltaic (OPV) device. Thus, we demonstrate that the impedance spectroscopy can an effective approach in characterizing the donor/acceptor interfaces, such that a direct correlation can be established between the morphology and the device performance of BHJ devices.
•BHJ of high efficient OPV with additive was analyzed via impedance spectroscopy.•The interface between donor/acceptor in BHJ layer was studied by simulated circuit.•Carrier lifetimes was calculated from simulated elements and correspond to OPV performance.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.solmat.2014.05.049</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-2853-2741</orcidid><orcidid>https://orcid.org/0000-0003-2059-0290</orcidid></addata></record> |
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subjects | Additives Applied sciences Bulk heterojuction Contact Devices Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Energy Exact sciences and technology Impedance spectroscopy Interface Morphology Natural energy OPV Photoelectric conversion Photovoltaic cells Photovoltaic conversion Solar cells Solar cells. Photoelectrochemical cells Solar energy |
title | The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy |
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