The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy

1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′)dithiophene-2,6...

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Veröffentlicht in:Solar energy materials and solar cells 2014-11, Vol.130, p.20-26
Hauptverfasser: Yao, En-Ping, Chen, Chun-Chao, Gao, Jing, Liu, Yongsheng, Chen, Qi, Cai, Min, Hsu, Wei-Chou, Hong, Ziruo, Li, Gang, Yang, Yang
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container_issue
container_start_page 20
container_title Solar energy materials and solar cells
container_volume 130
creator Yao, En-Ping
Chen, Chun-Chao
Gao, Jing
Liu, Yongsheng
Chen, Qi
Cai, Min
Hsu, Wei-Chou
Hong, Ziruo
Li, Gang
Yang, Yang
description 1, 8-Diiodooctane (DIO) has been known for its role of improving the polymer morphology and enhancing performance of polymer bulk heterojunction (BHJ) solar cell. In this work, the impedance spectroscopy was used to investigate the interface of poly(4,8-bis-alkyloxybenzo(1,2-b:4,5-b′)dithiophene-2,6-diyl-alt- (alkyl thieno(3,4-b) thiophene-2-carboxylate)-2,6-diyl) (PBDTTT-C):PC70BM in BHJ with DIO as additive. Based on our results, we were able to simulate the device into an equivalent circuit model, which allows us to conveniently analyze the organic/organic interfacial contact in the organic photovoltaic (OPV) device. Thus, we demonstrate that the impedance spectroscopy can an effective approach in characterizing the donor/acceptor interfaces, such that a direct correlation can be established between the morphology and the device performance of BHJ devices. •BHJ of high efficient OPV with additive was analyzed via impedance spectroscopy.•The interface between donor/acceptor in BHJ layer was studied by simulated circuit.•Carrier lifetimes was calculated from simulated elements and correspond to OPV performance.
doi_str_mv 10.1016/j.solmat.2014.05.049
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subjects Additives
Applied sciences
Bulk heterojuction
Contact
Devices
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Energy
Exact sciences and technology
Impedance spectroscopy
Interface
Morphology
Natural energy
OPV
Photoelectric conversion
Photovoltaic cells
Photovoltaic conversion
Solar cells
Solar cells. Photoelectrochemical cells
Solar energy
title The study of solvent additive effects in efficient polymer photovoltaics via impedance spectroscopy
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