Pincer‐Type Complexes for Catalytic (De)Hydrogenation and Transfer (De)Hydrogenation Reactions: Recent Progress
Pincer complexes are becoming increasingly important for organometallic chemistry and organic synthesis. Since numerous applications for such catalysts have been developed in recent decades, this Minireview covers progress in their use as catalysts for (de)hydrogenation and transfer (de)hydrogenatio...
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Veröffentlicht in: | Chemistry : a European journal 2015-08, Vol.21 (35), p.12226-12250 |
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creator | Werkmeister, Svenja Neumann, Jacob Junge, Kathrin Beller, Matthias |
description | Pincer complexes are becoming increasingly important for organometallic chemistry and organic synthesis. Since numerous applications for such catalysts have been developed in recent decades, this Minireview covers progress in their use as catalysts for (de)hydrogenation and transfer (de)hydrogenation reactions during the last four years. Aside from noble‐metal‐based pincer complexes, the corresponding base metal complexes are also highlighted and their applications summarized.
Pincers of power: This minireview is focused on the recent progress of the application of various precious and non‐precious metal pincer‐type catalysts. Besides hydrogenation reactions, their utilization for dehydrogenation and transfer (de)hydrogenation reactions is also described. Especially, but not exclusively, the usage of ruthenium and iron pincer complexes is highlighted for CC, CN, and CO bond transformations. |
doi_str_mv | 10.1002/chem.201500937 |
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Pincers of power: This minireview is focused on the recent progress of the application of various precious and non‐precious metal pincer‐type catalysts. Besides hydrogenation reactions, their utilization for dehydrogenation and transfer (de)hydrogenation reactions is also described. Especially, but not exclusively, the usage of ruthenium and iron pincer complexes is highlighted for CC, CN, and CO bond transformations.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201500937</identifier><identifier>PMID: 26179375</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag</publisher><subject>Bonding ; Catalysis ; Catalysts ; Chemistry ; dehydrogenation ; homogeneous catalysis ; Hydrogenation ; Iron ; Metalorganic compounds ; pincer complexes ; Ruthenium ; transfer hydrogenation ; Transformations</subject><ispartof>Chemistry : a European journal, 2015-08, Vol.21 (35), p.12226-12250</ispartof><rights>2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5097-5dfb8aef00cf294d10d065eb263729a1c9e2bfe134e357bae857ef6daf5e1a2b3</citedby><cites>FETCH-LOGICAL-c5097-5dfb8aef00cf294d10d065eb263729a1c9e2bfe134e357bae857ef6daf5e1a2b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201500937$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201500937$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26179375$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Werkmeister, Svenja</creatorcontrib><creatorcontrib>Neumann, Jacob</creatorcontrib><creatorcontrib>Junge, Kathrin</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><title>Pincer‐Type Complexes for Catalytic (De)Hydrogenation and Transfer (De)Hydrogenation Reactions: Recent Progress</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Pincer complexes are becoming increasingly important for organometallic chemistry and organic synthesis. Since numerous applications for such catalysts have been developed in recent decades, this Minireview covers progress in their use as catalysts for (de)hydrogenation and transfer (de)hydrogenation reactions during the last four years. Aside from noble‐metal‐based pincer complexes, the corresponding base metal complexes are also highlighted and their applications summarized.
Pincers of power: This minireview is focused on the recent progress of the application of various precious and non‐precious metal pincer‐type catalysts. Besides hydrogenation reactions, their utilization for dehydrogenation and transfer (de)hydrogenation reactions is also described. Especially, but not exclusively, the usage of ruthenium and iron pincer complexes is highlighted for CC, CN, and CO bond transformations.</description><subject>Bonding</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>dehydrogenation</subject><subject>homogeneous catalysis</subject><subject>Hydrogenation</subject><subject>Iron</subject><subject>Metalorganic compounds</subject><subject>pincer complexes</subject><subject>Ruthenium</subject><subject>transfer hydrogenation</subject><subject>Transformations</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqN0ctqGzEUBmBREmon7TbLMJBNshjnSBpJnuzKNKkDDg3FXQ8azVE6Zi62NKadXR4hz5gnqYxzgRJIVzpwPv1I_IQcUZhQAHZufmEzYUAFQMrVBzKmgtGYKyn2yBjSRMVS8HREDrxfQjCS849kxCRVgYsxWd9WrUH3eP-wGFYYZV2zqvEP-sh2Lsp0r-uhr0x0-hXPZkPpujtsdV91baTbMlo43XqL7o31D9RmO_iLMBps--g2bB16_4nsW117_Px0HpKfV5eLbBbPv3-7zr7MYyMgVbEobTHVaAGMZWlSUihBCiyY5IqlmpoUWWGR8gS5UIXGqVBoZamtQKpZwQ_J6S535br1Bn2fN5U3WNe6xW7jc6qmksokYfAfFITiCSgV6Mk_dNltXBs-slVJeJqkPKjJThnXee_Q5itXNdoNOYV821u-7S1_6S1cOH6K3RQNli_8uagA0h34XdU4vBOXZ7PLm9fwvwdMpaw</recordid><startdate>20150824</startdate><enddate>20150824</enddate><creator>Werkmeister, Svenja</creator><creator>Neumann, Jacob</creator><creator>Junge, Kathrin</creator><creator>Beller, Matthias</creator><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20150824</creationdate><title>Pincer‐Type Complexes for Catalytic (De)Hydrogenation and Transfer (De)Hydrogenation Reactions: Recent Progress</title><author>Werkmeister, Svenja ; Neumann, Jacob ; Junge, Kathrin ; Beller, Matthias</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5097-5dfb8aef00cf294d10d065eb263729a1c9e2bfe134e357bae857ef6daf5e1a2b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Bonding</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>dehydrogenation</topic><topic>homogeneous catalysis</topic><topic>Hydrogenation</topic><topic>Iron</topic><topic>Metalorganic compounds</topic><topic>pincer complexes</topic><topic>Ruthenium</topic><topic>transfer hydrogenation</topic><topic>Transformations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Werkmeister, Svenja</creatorcontrib><creatorcontrib>Neumann, Jacob</creatorcontrib><creatorcontrib>Junge, Kathrin</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Werkmeister, Svenja</au><au>Neumann, Jacob</au><au>Junge, Kathrin</au><au>Beller, Matthias</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pincer‐Type Complexes for Catalytic (De)Hydrogenation and Transfer (De)Hydrogenation Reactions: Recent Progress</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2015-08-24</date><risdate>2015</risdate><volume>21</volume><issue>35</issue><spage>12226</spage><epage>12250</epage><pages>12226-12250</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>Pincer complexes are becoming increasingly important for organometallic chemistry and organic synthesis. Since numerous applications for such catalysts have been developed in recent decades, this Minireview covers progress in their use as catalysts for (de)hydrogenation and transfer (de)hydrogenation reactions during the last four years. Aside from noble‐metal‐based pincer complexes, the corresponding base metal complexes are also highlighted and their applications summarized.
Pincers of power: This minireview is focused on the recent progress of the application of various precious and non‐precious metal pincer‐type catalysts. Besides hydrogenation reactions, their utilization for dehydrogenation and transfer (de)hydrogenation reactions is also described. Especially, but not exclusively, the usage of ruthenium and iron pincer complexes is highlighted for CC, CN, and CO bond transformations.</abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag</pub><pmid>26179375</pmid><doi>10.1002/chem.201500937</doi><tpages>25</tpages></addata></record> |
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subjects | Bonding Catalysis Catalysts Chemistry dehydrogenation homogeneous catalysis Hydrogenation Iron Metalorganic compounds pincer complexes Ruthenium transfer hydrogenation Transformations |
title | Pincer‐Type Complexes for Catalytic (De)Hydrogenation and Transfer (De)Hydrogenation Reactions: Recent Progress |
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