Copper catalyzed Heck-like cyclizations of oxime esters

Copper catalyzed Heck-like cyclizations of oxime esters are described. Mechanistic studies indicate a reaction pathway that proceeds via the generation and cyclization of an intermediate that possesses iminyl radical character. To the best of our knowledge, this work encompasses the first examples o...

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Veröffentlicht in:	Chemical science (Cambridge) 2014-01, Vol.5 (6), p.2416-2421
Hauptverfasser:	Faulkner, Adele, Race, Nicholas J., Scott, James S., Bower, John F.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Copper Esters Olefins Oximes Precious metals Radicals Sustainability
Online-Zugang:	Volltext
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