Temperature Effects on the Photovoltaic Performance of Planar Structure Perovskite Solar Cells
Temperature effects of CH3NH3PbI3 perovskite solar cells having simple planar architecture were investigated on the crystal structure and photovoltaic performance. The obvious changes in the CH3NH3PbI3 crystal structure were found by varying the temperature as a consequence to the augmentation in la...
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Veröffentlicht in: | Chemistry letters 2015-11, Vol.44 (11), p.1557-1559 |
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creator | Cojocaru, Ludmila Uchida, Satoshi Sanehira, Yoshitaka Gonzalez-Pedro, Victoria Bisquert, Juan Nakazaki, Jotaro Kubo, Takaya Segawa, Hiroshi |
description | Temperature effects of CH3NH3PbI3 perovskite solar cells having simple planar architecture were investigated on the crystal structure and photovoltaic performance. The obvious changes in the CH3NH3PbI3 crystal structure were found by varying the temperature as a consequence to the augmentation in lattice parameters and expansion of the unit cell. The expansion of the crystal gave a serious influence on the performance of the solar cells, where the differences in the coefficients of the thermal expansion (CTEs) together with the lattice mismatch between TiO2 and perovskite materials might cause interfacial defects responsible for the deterioration in the photovoltaic performance. Interestingly, the hysteresis in the cubic phase is very small because of the less distorted angles of the CH3NH3PbI3 structure against the temperature fluctuation. |
doi_str_mv | 10.1246/cl.150781 |
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The obvious changes in the CH3NH3PbI3 crystal structure were found by varying the temperature as a consequence to the augmentation in lattice parameters and expansion of the unit cell. The expansion of the crystal gave a serious influence on the performance of the solar cells, where the differences in the coefficients of the thermal expansion (CTEs) together with the lattice mismatch between TiO2 and perovskite materials might cause interfacial defects responsible for the deterioration in the photovoltaic performance. Interestingly, the hysteresis in the cubic phase is very small because of the less distorted angles of the CH3NH3PbI3 structure against the temperature fluctuation.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.150781</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Crystal defects ; Crystal lattices ; Crystal structure ; Perovskite Solar Cells ; Perovskites ; Photovoltaic cells ; Solar cells ; Thermal expansion ; Titanium dioxide</subject><ispartof>Chemistry letters, 2015-11, Vol.44 (11), p.1557-1559</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2015</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c537t-be38b8befb1fc79ed1cd2a34d774af009a146c2ffcdd4c631e170adb47f959933</citedby><cites>FETCH-LOGICAL-c537t-be38b8befb1fc79ed1cd2a34d774af009a146c2ffcdd4c631e170adb47f959933</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Cojocaru, Ludmila</creatorcontrib><creatorcontrib>Uchida, Satoshi</creatorcontrib><creatorcontrib>Sanehira, Yoshitaka</creatorcontrib><creatorcontrib>Gonzalez-Pedro, Victoria</creatorcontrib><creatorcontrib>Bisquert, Juan</creatorcontrib><creatorcontrib>Nakazaki, Jotaro</creatorcontrib><creatorcontrib>Kubo, Takaya</creatorcontrib><creatorcontrib>Segawa, Hiroshi</creatorcontrib><title>Temperature Effects on the Photovoltaic Performance of Planar Structure Perovskite Solar Cells</title><title>Chemistry letters</title><addtitle>Chemistry Letters</addtitle><description>Temperature effects of CH3NH3PbI3 perovskite solar cells having simple planar architecture were investigated on the crystal structure and photovoltaic performance. The obvious changes in the CH3NH3PbI3 crystal structure were found by varying the temperature as a consequence to the augmentation in lattice parameters and expansion of the unit cell. The expansion of the crystal gave a serious influence on the performance of the solar cells, where the differences in the coefficients of the thermal expansion (CTEs) together with the lattice mismatch between TiO2 and perovskite materials might cause interfacial defects responsible for the deterioration in the photovoltaic performance. Interestingly, the hysteresis in the cubic phase is very small because of the less distorted angles of the CH3NH3PbI3 structure against the temperature fluctuation.</description><subject>Crystal defects</subject><subject>Crystal lattices</subject><subject>Crystal structure</subject><subject>Perovskite Solar Cells</subject><subject>Perovskites</subject><subject>Photovoltaic cells</subject><subject>Solar cells</subject><subject>Thermal expansion</subject><subject>Titanium dioxide</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNplkM9LwzAYhoMoOKcH_4OAFz10Jk2atEcZ_oKBg82rJU2_sM62mUk62H9v5nYQPX2H93kfXj6ErimZ0JSLe91OaEZkTk_QiDKeJ0TS7BSNCBMikSRNz9GF92tCSF6wdIQ-ltBtwKkwOMCPxoAOHtsehxXg-coGu7VtUI3Gc3DGuk71GrA1eN6qXjm8CG7QP92Y263_bALghW1jNIW29ZfozKjWw9XxjtH70-Ny-pLM3p5fpw-zRGdMhqQClld5BaaiRssCaqrrVDFeS8mVIaRQlAudGqPrmmvBKFBJVF1xaYqsKBgbo9uDd-Ps1wA-lF3jdVygerCDL6nMBY09XkT05g-6toPr47pIZawgQoi98O5AaWe9d2DKjWs65XYlJeX-06Vuy8OnIyuO7Aq6RkeT1Q2E3VptVP_L_q_4DQO4hI4</recordid><startdate>20151105</startdate><enddate>20151105</enddate><creator>Cojocaru, Ludmila</creator><creator>Uchida, Satoshi</creator><creator>Sanehira, Yoshitaka</creator><creator>Gonzalez-Pedro, Victoria</creator><creator>Bisquert, Juan</creator><creator>Nakazaki, Jotaro</creator><creator>Kubo, Takaya</creator><creator>Segawa, Hiroshi</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20151105</creationdate><title>Temperature Effects on the Photovoltaic Performance of Planar Structure Perovskite Solar Cells</title><author>Cojocaru, Ludmila ; Uchida, Satoshi ; Sanehira, Yoshitaka ; Gonzalez-Pedro, Victoria ; Bisquert, Juan ; Nakazaki, Jotaro ; Kubo, Takaya ; Segawa, Hiroshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c537t-be38b8befb1fc79ed1cd2a34d774af009a146c2ffcdd4c631e170adb47f959933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Crystal defects</topic><topic>Crystal lattices</topic><topic>Crystal structure</topic><topic>Perovskite Solar Cells</topic><topic>Perovskites</topic><topic>Photovoltaic cells</topic><topic>Solar cells</topic><topic>Thermal expansion</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cojocaru, Ludmila</creatorcontrib><creatorcontrib>Uchida, Satoshi</creatorcontrib><creatorcontrib>Sanehira, Yoshitaka</creatorcontrib><creatorcontrib>Gonzalez-Pedro, Victoria</creatorcontrib><creatorcontrib>Bisquert, Juan</creatorcontrib><creatorcontrib>Nakazaki, Jotaro</creatorcontrib><creatorcontrib>Kubo, Takaya</creatorcontrib><creatorcontrib>Segawa, Hiroshi</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cojocaru, Ludmila</au><au>Uchida, Satoshi</au><au>Sanehira, Yoshitaka</au><au>Gonzalez-Pedro, Victoria</au><au>Bisquert, Juan</au><au>Nakazaki, Jotaro</au><au>Kubo, Takaya</au><au>Segawa, Hiroshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature Effects on the Photovoltaic Performance of Planar Structure Perovskite Solar Cells</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>2015-11-05</date><risdate>2015</risdate><volume>44</volume><issue>11</issue><spage>1557</spage><epage>1559</epage><pages>1557-1559</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Temperature effects of CH3NH3PbI3 perovskite solar cells having simple planar architecture were investigated on the crystal structure and photovoltaic performance. The obvious changes in the CH3NH3PbI3 crystal structure were found by varying the temperature as a consequence to the augmentation in lattice parameters and expansion of the unit cell. The expansion of the crystal gave a serious influence on the performance of the solar cells, where the differences in the coefficients of the thermal expansion (CTEs) together with the lattice mismatch between TiO2 and perovskite materials might cause interfacial defects responsible for the deterioration in the photovoltaic performance. Interestingly, the hysteresis in the cubic phase is very small because of the less distorted angles of the CH3NH3PbI3 structure against the temperature fluctuation.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.150781</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
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source | Oxford University Press Journals All Titles (1996-Current) |
subjects | Crystal defects Crystal lattices Crystal structure Perovskite Solar Cells Perovskites Photovoltaic cells Solar cells Thermal expansion Titanium dioxide |
title | Temperature Effects on the Photovoltaic Performance of Planar Structure Perovskite Solar Cells |
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