HREELS Evaluation of Coronene Monolayer Adsorption on Au(111) as the First Base Layer to Achieve Coordination Programming

To achieve coordination programming at an electrode surface, the first functional layer is highly important. In this study, high-resolution electron energy-loss spectroscopy (HREELS) was used to investigate coronene monolayer adsorption on a Au(111) substrate at 300 K. In the spectra, only a band at...

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Veröffentlicht in:	Chemistry letters 2014, Vol.43 (8), p.1340-1342
Hauptverfasser:	Nishiyama, Katsuhiko, Harada, Hiroshi, Yoshimoto, Soichiro, Taniguchi, Isao, Yamada, Taro
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Band spectra Coordination Programming Electrodes Monolayers Programming Spectra Surface chemistry Vibration mode
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creator	Nishiyama, Katsuhiko Harada, Hiroshi Yoshimoto, Soichiro Taniguchi, Isao Yamada, Taro
description	To achieve coordination programming at an electrode surface, the first functional layer is highly important. In this study, high-resolution electron energy-loss spectroscopy (HREELS) was used to investigate coronene monolayer adsorption on a Au(111) substrate at 300 K. In the spectra, only a band attributable to the out-of-plane vibration mode was observed, suggesting that coronene molecules adsorb on the substrate with a flat orientation. Furthermore, the HREEL spectra showed that the coronene monolayer was stable even after heating to 400 K.
doi_str_mv	10.1246/cl.140266
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In this study, high-resolution electron energy-loss spectroscopy (HREELS) was used to investigate coronene monolayer adsorption on a Au(111) substrate at 300 K. In the spectra, only a band attributable to the out-of-plane vibration mode was observed, suggesting that coronene molecules adsorb on the substrate with a flat orientation. Furthermore, the HREEL spectra showed that the coronene monolayer was stable even after heating to 400 K.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.140266</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record>
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Adsorption Band spectra Coordination Programming Electrodes Monolayers Programming Spectra Surface chemistry Vibration mode
title	HREELS Evaluation of Coronene Monolayer Adsorption on Au(111) as the First Base Layer to Achieve Coordination Programming
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