Photobase Generators Liberating Two Bases by Absorbing One Photon and Their Application to Photosensitive Materials

Photobase Generators Liberating Two Bases by Absorbing One Photon and Their Application to Photosensitive Materials

We propose a photobase generator (PBG) that liberates two bases by absorbing one photon. Phototriggered decarboxylation proceeds first to generate one base, and subsequently the unstable reaction intermediate is thermally decarboxylated to generate another base. It was found that the photosensitivit...

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Veröffentlicht in:Chemistry letters 2015-09, Vol.44 (9), p.1194-1196
Hauptverfasser: Arimitsu, Koji, Maruyama, Yuya, Furutani, Masahiro
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Sprache:eng
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Absorption
Decarboxylation
Generators
Photons
Photosensitivity
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container_issue 9
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container_title Chemistry letters
container_volume 44
creator Arimitsu, Koji
Maruyama, Yuya
Furutani, Masahiro
description We propose a photobase generator (PBG) that liberates two bases by absorbing one photon. Phototriggered decarboxylation proceeds first to generate one base, and subsequently the unstable reaction intermediate is thermally decarboxylated to generate another base. It was found that the photosensitivity of poly(glycidyl methacrylate) films containing the PBG is much higher than that of films containing a conventional PBG that generates one base by absorbing one photon.
doi_str_mv 10.1246/cl.150405
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source Oxford University Press Journals All Titles (1996-Current)
subjects Absorption
Decarboxylation
Generators
Photons
Photosensitivity
title Photobase Generators Liberating Two Bases by Absorbing One Photon and Their Application to Photosensitive Materials
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