Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts

Hydrosilylation of CO2 catalyzed by simple fluoride and carbonate salts, such as CsF and K2CO3, is described. Total yields up to 87% for the formylated product were achieved. Mechanistic investigations indicate the reaction proceeds via the formation of an active formate species. This catalytic syst...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemistry letters 2015-09, Vol.44 (9), p.1217-1219
Hauptverfasser:	Motokura, Ken, Naijo, Masaki, Yamaguchi, Sho, Miyaji, Akimitsu, Baba, Toshihide
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Carbon dioxide Carbonates Catalysis Fluorides Formations Synthesis Transformations
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	1219
container_issue	9
container_start_page	1217
container_title	Chemistry letters
container_volume	44
creator	Motokura, Ken Naijo, Masaki Yamaguchi, Sho Miyaji, Akimitsu Baba, Toshihide
description	Hydrosilylation of CO2 catalyzed by simple fluoride and carbonate salts, such as CsF and K2CO3, is described. Total yields up to 87% for the formylated product were achieved. Mechanistic investigations indicate the reaction proceeds via the formation of an active formate species. This catalytic system was also found to be applicable to formamide synthesis from amines, CO2, and hydrosilane.
doi_str_mv	10.1246/cl.150510
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1786161593</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3913007721</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-fac9c5c2ab8bed1134d55b7eef6c877880e87b838669234ec5cf94201abcec953</originalsourceid><addsrcrecordid>eNpl0E1LxDAQBuAgCq4fB_9BwIseqkmz-ehRFtcVBMHVc0nTKWZJmzVJlfrrjawH0dNcnnl5ZxA6o-SKlnNxbdwV5YRTsodmlM1VQSTl-2hGmBCFJGV5iI5i3BBCVMXKGWqeoB1Nsu-An4MeYudDr5P1A_YdXjyW-MOmV7ya2uCjdXqAiBc6aTd9QoubCa9tv3WAl270wbaA9dBmEBo_6AR4rV2KJ-ig0y7C6c88Ri_L2-fFqnh4vLtf3DwUhjGZik6bynBT6kY10NJcvuW8kQCdMEpKpQgo2SimhKhKNodsu2peEqobA6bi7Bhd7HK3wb-NEFPd22jAfbf2Y6ypVIIKyiuW6fkfuvFjGHK7rDirCBeVzOpyp0w-Pgbo6m2wvQ5TTUn9_e3auHr37WzFj32F3pqc5I2FNG30Vg-_0v8tfgEceoTX</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1753905697</pqid></control><display><type>article</type><title>Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts</title><source>Oxford University Press Journals Current</source><creator>Motokura, Ken ; Naijo, Masaki ; Yamaguchi, Sho ; Miyaji, Akimitsu ; Baba, Toshihide</creator><creatorcontrib>Motokura, Ken ; Naijo, Masaki ; Yamaguchi, Sho ; Miyaji, Akimitsu ; Baba, Toshihide</creatorcontrib><description>Hydrosilylation of CO2 catalyzed by simple fluoride and carbonate salts, such as CsF and K2CO3, is described. Total yields up to 87% for the formylated product were achieved. Mechanistic investigations indicate the reaction proceeds via the formation of an active formate species. This catalytic system was also found to be applicable to formamide synthesis from amines, CO2, and hydrosilane.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.150510</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Amines ; Carbon dioxide ; Carbonates ; Catalysis ; Fluorides ; Formations ; Synthesis ; Transformations</subject><ispartof>Chemistry letters, 2015-09, Vol.44 (9), p.1217-1219</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2015</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-fac9c5c2ab8bed1134d55b7eef6c877880e87b838669234ec5cf94201abcec953</citedby><cites>FETCH-LOGICAL-c337t-fac9c5c2ab8bed1134d55b7eef6c877880e87b838669234ec5cf94201abcec953</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Motokura, Ken</creatorcontrib><creatorcontrib>Naijo, Masaki</creatorcontrib><creatorcontrib>Yamaguchi, Sho</creatorcontrib><creatorcontrib>Miyaji, Akimitsu</creatorcontrib><creatorcontrib>Baba, Toshihide</creatorcontrib><title>Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts</title><title>Chemistry letters</title><addtitle>Chemistry Letters</addtitle><description>Hydrosilylation of CO2 catalyzed by simple fluoride and carbonate salts, such as CsF and K2CO3, is described. Total yields up to 87% for the formylated product were achieved. Mechanistic investigations indicate the reaction proceeds via the formation of an active formate species. This catalytic system was also found to be applicable to formamide synthesis from amines, CO2, and hydrosilane.</description><subject>Amines</subject><subject>Carbon dioxide</subject><subject>Carbonates</subject><subject>Catalysis</subject><subject>Fluorides</subject><subject>Formations</subject><subject>Synthesis</subject><subject>Transformations</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpl0E1LxDAQBuAgCq4fB_9BwIseqkmz-ehRFtcVBMHVc0nTKWZJmzVJlfrrjawH0dNcnnl5ZxA6o-SKlnNxbdwV5YRTsodmlM1VQSTl-2hGmBCFJGV5iI5i3BBCVMXKGWqeoB1Nsu-An4MeYudDr5P1A_YdXjyW-MOmV7ya2uCjdXqAiBc6aTd9QoubCa9tv3WAl270wbaA9dBmEBo_6AR4rV2KJ-ig0y7C6c88Ri_L2-fFqnh4vLtf3DwUhjGZik6bynBT6kY10NJcvuW8kQCdMEpKpQgo2SimhKhKNodsu2peEqobA6bi7Bhd7HK3wb-NEFPd22jAfbf2Y6ypVIIKyiuW6fkfuvFjGHK7rDirCBeVzOpyp0w-Pgbo6m2wvQ5TTUn9_e3auHr37WzFj32F3pqc5I2FNG30Vg-_0v8tfgEceoTX</recordid><startdate>20150905</startdate><enddate>20150905</enddate><creator>Motokura, Ken</creator><creator>Naijo, Masaki</creator><creator>Yamaguchi, Sho</creator><creator>Miyaji, Akimitsu</creator><creator>Baba, Toshihide</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20150905</creationdate><title>Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts</title><author>Motokura, Ken ; Naijo, Masaki ; Yamaguchi, Sho ; Miyaji, Akimitsu ; Baba, Toshihide</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-fac9c5c2ab8bed1134d55b7eef6c877880e87b838669234ec5cf94201abcec953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Amines</topic><topic>Carbon dioxide</topic><topic>Carbonates</topic><topic>Catalysis</topic><topic>Fluorides</topic><topic>Formations</topic><topic>Synthesis</topic><topic>Transformations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Motokura, Ken</creatorcontrib><creatorcontrib>Naijo, Masaki</creatorcontrib><creatorcontrib>Yamaguchi, Sho</creatorcontrib><creatorcontrib>Miyaji, Akimitsu</creatorcontrib><creatorcontrib>Baba, Toshihide</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Motokura, Ken</au><au>Naijo, Masaki</au><au>Yamaguchi, Sho</au><au>Miyaji, Akimitsu</au><au>Baba, Toshihide</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts</atitle><jtitle>Chemistry letters</jtitle><addtitle>Chemistry Letters</addtitle><date>2015-09-05</date><risdate>2015</risdate><volume>44</volume><issue>9</issue><spage>1217</spage><epage>1219</epage><pages>1217-1219</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Hydrosilylation of CO2 catalyzed by simple fluoride and carbonate salts, such as CsF and K2CO3, is described. Total yields up to 87% for the formylated product were achieved. Mechanistic investigations indicate the reaction proceeds via the formation of an active formate species. This catalytic system was also found to be applicable to formamide synthesis from amines, CO2, and hydrosilane.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.150510</doi><tpages>3</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 0366-7022
ispartof	Chemistry letters, 2015-09, Vol.44 (9), p.1217-1219
issn	0366-7022 1348-0715
language	eng
recordid	cdi_proquest_miscellaneous_1786161593
source	Oxford University Press Journals Current
subjects	Amines Carbon dioxide Carbonates Catalysis Fluorides Formations Synthesis Transformations
title	Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T14%3A27%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Reductive%20Transformation%20of%20CO2%20with%20Hydrosilanes%20Catalyzed%20by%20Simple%20Fluoride%20and%20Carbonate%20Salts&rft.jtitle=Chemistry%20letters&rft.au=Motokura,%20Ken&rft.date=2015-09-05&rft.volume=44&rft.issue=9&rft.spage=1217&rft.epage=1219&rft.pages=1217-1219&rft.issn=0366-7022&rft.eissn=1348-0715&rft_id=info:doi/10.1246/cl.150510&rft_dat=%3Cproquest_cross%3E3913007721%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1753905697&rft_id=info:pmid/&rfr_iscdi=true