Development of a generic activation mode: nucleophilic alpha -substitution of ketones viaoxy-allyl cations

Oxy-allyl cations have been known as transient electrophilic species since they were first proposed as intermediates in the Favorskii rearrangement in 1894. Since that time, they also have been used as a mode of activation for [4 + 3] cycloadditions in a variety of natural product syntheses. In this...

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Veröffentlicht in:	Chemical science (Cambridge) 2013-07, Vol.4 (8), p.3075-3079
Hauptverfasser:	Vander Wal, Mark N, Dilger, Andrew K, MacMillan, David WC
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Carbon-carbon composites Catalysis Cations Formations Ketones Nucleophiles
Online-Zugang:	Volltext
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