Organochlorine pesticides (OCPs) in the Indus River catchment area, Pakistan: Status, soil–air exchange and black carbon mediated distribution
Organochlorine pesticides (OCPs) were investigated in passive air and soil samples from the catchment area of the Indus River, Pakistan. ∑15OCPs ranged between 0.68 and 13.47 ng g−1 in soil and 375.1–1975 pg mˉ3 in air. HCHs and DDTs were more prevalent in soil and air compartments. Composition prof...
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| Veröffentlicht in: | Chemosphere (Oxford) 2016-06, Vol.152, p.292-300 |
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| creator | Bajwa, Anam Ali, Usman Mahmood, Adeel Chaudhry, Muhammad Jamshed Iqbal Syed, Jabir Hussain Li, Jun Zhang, Gan Jones, Kevin C. Malik, Riffat Naseem |
| description | Organochlorine pesticides (OCPs) were investigated in passive air and soil samples from the catchment area of the Indus River, Pakistan. ∑15OCPs ranged between 0.68 and 13.47 ng g−1 in soil and 375.1–1975 pg mˉ3 in air. HCHs and DDTs were more prevalent in soil and air compartments. Composition profile indicated that β-HCH and p,p'-DDE were the dominant of all metabolites among HCHs and DDTs respectively. Moreover, fBC and fTOC were assessed and evaluated their potential role in the distribution status of OCPs. The fTOC and fBC ranged between 0.77 and 2.43 and 0.04–0.30% respectively in soil. Regression analysis showed the strong influence of fBC than fTOC on the distribution of OCPs in the Indus River catchment area soil. Equilibrium status was observed for β-HCH, δ-HCH, p,p'-DDD, o,p'-DDT, TC, HCB and Heptachlor with ff ranged between 0.3 and 0.59 while assessing the soil–air exchange of OCPs.
•Black carbon showed influential role in distribution status of organochlorine pesticides in the catchment area of the Indus River.•Fugacity fractions showed equilibrium status of OCPs in soil and air of the Indus River catchment area.•HCHs and DDTs were the prevalent organochlorine pesticides in soil and air of the Indus River catchment area. |
| doi_str_mv | 10.1016/j.chemosphere.2016.01.024 |
| format | Article |
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•Black carbon showed influential role in distribution status of organochlorine pesticides in the catchment area of the Indus River.•Fugacity fractions showed equilibrium status of OCPs in soil and air of the Indus River catchment area.•HCHs and DDTs were the prevalent organochlorine pesticides in soil and air of the Indus River catchment area.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/j.chemosphere.2016.01.024</identifier><identifier>PMID: 26978705</identifier><language>eng</language><publisher>England: Elsevier Ltd</publisher><subject>Adsorption ; Black carbon ; Brackish ; Carbon - chemistry ; DDT - analysis ; Dichlorodiphenyl Dichloroethylene - analysis ; Environmental Monitoring - methods ; Hydrocarbons, Chlorinated - analysis ; Indus River ; Lindane - analysis ; OCPs ; Pakistan ; Pesticides - analysis ; Rivers - chemistry ; Soil - chemistry ; Soil Pollutants - analysis ; Soil–air exchange ; Soot - analysis ; Total organic carbon</subject><ispartof>Chemosphere (Oxford), 2016-06, Vol.152, p.292-300</ispartof><rights>2016 Elsevier Ltd</rights><rights>Copyright © 2016 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c410t-28e22b13653bcc9563e887b497f6d9cf8d45c215bcb57915d70d18f01d69a4c63</citedby><cites>FETCH-LOGICAL-c410t-28e22b13653bcc9563e887b497f6d9cf8d45c215bcb57915d70d18f01d69a4c63</cites><orcidid>0000-0003-0889-5286</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0045653516300248$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26978705$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bajwa, Anam</creatorcontrib><creatorcontrib>Ali, Usman</creatorcontrib><creatorcontrib>Mahmood, Adeel</creatorcontrib><creatorcontrib>Chaudhry, Muhammad Jamshed Iqbal</creatorcontrib><creatorcontrib>Syed, Jabir Hussain</creatorcontrib><creatorcontrib>Li, Jun</creatorcontrib><creatorcontrib>Zhang, Gan</creatorcontrib><creatorcontrib>Jones, Kevin C.</creatorcontrib><creatorcontrib>Malik, Riffat Naseem</creatorcontrib><title>Organochlorine pesticides (OCPs) in the Indus River catchment area, Pakistan: Status, soil–air exchange and black carbon mediated distribution</title><title>Chemosphere (Oxford)</title><addtitle>Chemosphere</addtitle><description>Organochlorine pesticides (OCPs) were investigated in passive air and soil samples from the catchment area of the Indus River, Pakistan. ∑15OCPs ranged between 0.68 and 13.47 ng g−1 in soil and 375.1–1975 pg mˉ3 in air. HCHs and DDTs were more prevalent in soil and air compartments. Composition profile indicated that β-HCH and p,p'-DDE were the dominant of all metabolites among HCHs and DDTs respectively. Moreover, fBC and fTOC were assessed and evaluated their potential role in the distribution status of OCPs. The fTOC and fBC ranged between 0.77 and 2.43 and 0.04–0.30% respectively in soil. Regression analysis showed the strong influence of fBC than fTOC on the distribution of OCPs in the Indus River catchment area soil. Equilibrium status was observed for β-HCH, δ-HCH, p,p'-DDD, o,p'-DDT, TC, HCB and Heptachlor with ff ranged between 0.3 and 0.59 while assessing the soil–air exchange of OCPs.
•Black carbon showed influential role in distribution status of organochlorine pesticides in the catchment area of the Indus River.•Fugacity fractions showed equilibrium status of OCPs in soil and air of the Indus River catchment area.•HCHs and DDTs were the prevalent organochlorine pesticides in soil and air of the Indus River catchment area.</description><subject>Adsorption</subject><subject>Black carbon</subject><subject>Brackish</subject><subject>Carbon - chemistry</subject><subject>DDT - analysis</subject><subject>Dichlorodiphenyl Dichloroethylene - analysis</subject><subject>Environmental Monitoring - methods</subject><subject>Hydrocarbons, Chlorinated - analysis</subject><subject>Indus River</subject><subject>Lindane - analysis</subject><subject>OCPs</subject><subject>Pakistan</subject><subject>Pesticides - analysis</subject><subject>Rivers - chemistry</subject><subject>Soil - chemistry</subject><subject>Soil Pollutants - analysis</subject><subject>Soil–air exchange</subject><subject>Soot - analysis</subject><subject>Total organic carbon</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkctq3DAUhkVpaSZpX6GouxRiV5It2-ouDL0EAhN6WQtZOo41saWpJId210cI9A37JNUwaegyqwOH79fh14fQa0pKSmjzdlvqEWYfdyMEKFlelYSWhNVP0Ip2rSgoE91TtCKk5kXDK36EjmPcEpJJLp6jI9aItmsJX6G7TbhWzutx8sE6wDuIyWprIOLTzfoqvsHW4TQCvnBmifizvYWAtUp6nMElrAKoM3ylbmxMyr3DX5JKSzzD0dvpz6_fygYMP_So3DVg5QzuJ6Vvcj703uEZjFUJDDY5HWy_JOvdC_RsUFOEl_fzBH378P7r-lNxufl4sT6_LHRNSSpYB4z1tMrteq0FbyrouravRTs0RuihMzXXjPJe97wVlJuWGNoNhJpGqFo31Qk6Pby7C_77klvL2UYN06Qc-CVK2nac8YrRPSoOqA4-xgCD3AU7q_BTUiL3QuRW_idE7oVIQmUWkrOv7s8sfe77kPxnIAPrAwC57K2FIKO24HT-mwA6SePtI878BUIypSU</recordid><startdate>201606</startdate><enddate>201606</enddate><creator>Bajwa, Anam</creator><creator>Ali, Usman</creator><creator>Mahmood, Adeel</creator><creator>Chaudhry, Muhammad Jamshed Iqbal</creator><creator>Syed, Jabir Hussain</creator><creator>Li, Jun</creator><creator>Zhang, Gan</creator><creator>Jones, Kevin C.</creator><creator>Malik, Riffat Naseem</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7ST</scope><scope>7TV</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-0889-5286</orcidid></search><sort><creationdate>201606</creationdate><title>Organochlorine pesticides (OCPs) in the Indus River catchment area, Pakistan: Status, soil–air exchange and black carbon mediated distribution</title><author>Bajwa, Anam ; Ali, Usman ; Mahmood, Adeel ; Chaudhry, Muhammad Jamshed Iqbal ; Syed, Jabir Hussain ; Li, Jun ; Zhang, Gan ; Jones, Kevin C. ; Malik, Riffat Naseem</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c410t-28e22b13653bcc9563e887b497f6d9cf8d45c215bcb57915d70d18f01d69a4c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Adsorption</topic><topic>Black carbon</topic><topic>Brackish</topic><topic>Carbon - chemistry</topic><topic>DDT - analysis</topic><topic>Dichlorodiphenyl Dichloroethylene - analysis</topic><topic>Environmental Monitoring - methods</topic><topic>Hydrocarbons, Chlorinated - analysis</topic><topic>Indus River</topic><topic>Lindane - analysis</topic><topic>OCPs</topic><topic>Pakistan</topic><topic>Pesticides - analysis</topic><topic>Rivers - chemistry</topic><topic>Soil - chemistry</topic><topic>Soil Pollutants - analysis</topic><topic>Soil–air exchange</topic><topic>Soot - analysis</topic><topic>Total organic carbon</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bajwa, Anam</creatorcontrib><creatorcontrib>Ali, Usman</creatorcontrib><creatorcontrib>Mahmood, Adeel</creatorcontrib><creatorcontrib>Chaudhry, Muhammad Jamshed Iqbal</creatorcontrib><creatorcontrib>Syed, Jabir Hussain</creatorcontrib><creatorcontrib>Li, Jun</creatorcontrib><creatorcontrib>Zhang, Gan</creatorcontrib><creatorcontrib>Jones, Kevin C.</creatorcontrib><creatorcontrib>Malik, Riffat Naseem</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Environment Abstracts</collection><collection>Pollution Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Environment Abstracts</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bajwa, Anam</au><au>Ali, Usman</au><au>Mahmood, Adeel</au><au>Chaudhry, Muhammad Jamshed Iqbal</au><au>Syed, Jabir Hussain</au><au>Li, Jun</au><au>Zhang, Gan</au><au>Jones, Kevin C.</au><au>Malik, Riffat Naseem</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Organochlorine pesticides (OCPs) in the Indus River catchment area, Pakistan: Status, soil–air exchange and black carbon mediated distribution</atitle><jtitle>Chemosphere (Oxford)</jtitle><addtitle>Chemosphere</addtitle><date>2016-06</date><risdate>2016</risdate><volume>152</volume><spage>292</spage><epage>300</epage><pages>292-300</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><abstract>Organochlorine pesticides (OCPs) were investigated in passive air and soil samples from the catchment area of the Indus River, Pakistan. ∑15OCPs ranged between 0.68 and 13.47 ng g−1 in soil and 375.1–1975 pg mˉ3 in air. HCHs and DDTs were more prevalent in soil and air compartments. Composition profile indicated that β-HCH and p,p'-DDE were the dominant of all metabolites among HCHs and DDTs respectively. Moreover, fBC and fTOC were assessed and evaluated their potential role in the distribution status of OCPs. The fTOC and fBC ranged between 0.77 and 2.43 and 0.04–0.30% respectively in soil. Regression analysis showed the strong influence of fBC than fTOC on the distribution of OCPs in the Indus River catchment area soil. Equilibrium status was observed for β-HCH, δ-HCH, p,p'-DDD, o,p'-DDT, TC, HCB and Heptachlor with ff ranged between 0.3 and 0.59 while assessing the soil–air exchange of OCPs.
•Black carbon showed influential role in distribution status of organochlorine pesticides in the catchment area of the Indus River.•Fugacity fractions showed equilibrium status of OCPs in soil and air of the Indus River catchment area.•HCHs and DDTs were the prevalent organochlorine pesticides in soil and air of the Indus River catchment area.</abstract><cop>England</cop><pub>Elsevier Ltd</pub><pmid>26978705</pmid><doi>10.1016/j.chemosphere.2016.01.024</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-0889-5286</orcidid></addata></record> |
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| ispartof | Chemosphere (Oxford), 2016-06, Vol.152, p.292-300 |
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| subjects | Adsorption Black carbon Brackish Carbon - chemistry DDT - analysis Dichlorodiphenyl Dichloroethylene - analysis Environmental Monitoring - methods Hydrocarbons, Chlorinated - analysis Indus River Lindane - analysis OCPs Pakistan Pesticides - analysis Rivers - chemistry Soil - chemistry Soil Pollutants - analysis Soil–air exchange Soot - analysis Total organic carbon |
| title | Organochlorine pesticides (OCPs) in the Indus River catchment area, Pakistan: Status, soil–air exchange and black carbon mediated distribution |
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