Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes

The vastly increasing application of chiral Cp ligands in asymmetric catalysis results in growing demand for novel chiral Cp ligands. Herein, we report a new class of chiral Cp ligands based on 1,1′-spirobiindane, a privileged scaffold for chiral ligands and catalysts. The corresponding Rh complexes...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-04, Vol.138 (16), p.5242-5245
Hauptverfasser:	Zheng, Jun, Cui, Wen-Jun, Zheng, Chao, You, Shu-Li
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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