In situ generated polysiloxanes stabilizing μ3-oxo bridged Sb3 triangles

In situ generated polysiloxanes stabilizing μ3-oxo bridged Sb3 triangles

The reaction of RSbO3H2 with t-butylsilanetriol has led to the isolation of organoantimony(v) based molecular triangles stabilized by siloxane frameworks. Depending on the reaction conditions employed or the substituents present on the antimony atom, either a combination of a disiloxane and a tetras...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016-04, Vol.45 (16), p.6963-6967
Hauptverfasser: Santhana Raj Prabhu, M, Ugandhar, Uppara, Baskar, Viswanathan
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container_issue 16
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Santhana Raj Prabhu, M
Ugandhar, Uppara
Baskar, Viswanathan
description The reaction of RSbO3H2 with t-butylsilanetriol has led to the isolation of organoantimony(v) based molecular triangles stabilized by siloxane frameworks. Depending on the reaction conditions employed or the substituents present on the antimony atom, either a combination of a disiloxane and a tetrasiloxane framework or a trisiloxane framework was generated in situ leading to the stabilization of the Sb3 triangle.
doi_str_mv 10.1039/c5dt01590a
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title In situ generated polysiloxanes stabilizing μ3-oxo bridged Sb3 triangles
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