Combined Electrical and Optical Characterization of Polydiacetylene

Combined Electrical and Optical Characterization of Polydiacetylene

Polydiacetylene (PDA) is a conductive polymer that has mechanochromism. When the polymer is exposed to mechanical stresses, change in temperature (thermochromism), pH (ionochromism), and so forth, the structural perturbation can be seen by the change in its color. Although it presents interesting el...

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Veröffentlicht in:The journal of physical chemistry. B 2016-04, Vol.120 (14), p.3511-3515
Hauptverfasser: Girard-Reydet, Clement, Ortuso, Roberto Diego, Tsemperouli, Maria, Sugihara, Kaori
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container_issue 14
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container_title The journal of physical chemistry. B
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creator Girard-Reydet, Clement
Ortuso, Roberto Diego
Tsemperouli, Maria
Sugihara, Kaori
description Polydiacetylene (PDA) is a conductive polymer that has mechanochromism. When the polymer is exposed to mechanical stresses, change in temperature (thermochromism), pH (ionochromism), and so forth, the structural perturbation can be seen by the change in its color. Although it presents interesting electrical and optical properties, the relationship between these signals has rarely been investigated. We studied the correlation between the electrical conductivity and the absorption spectra of PDA. Upon UV irradiation, PDA absorption spectra presented a blue shift, which coincided with the decrease in the electrical conductivity.
doi_str_mv 10.1021/acs.jpcb.6b02229
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title Combined Electrical and Optical Characterization of Polydiacetylene
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