Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO

Many transition‐metal complexes and some metal‐free compounds are able to bind carbon monoxide, a molecule which has the strongest chemical bond in nature. However, very few of them have been shown to induce the cleavage of its C−O bond and even fewer are those that are able to transform CO into org...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-04, Vol.55 (15), p.4707-4710
Hauptverfasser:	Batsanov, Andrei S., Cabeza, Javier A., Crestani, Marco G., Fructos, Manuel R., García-Álvarez, Pablo, Gille, Marie, Lin, Zhenyang, Marder, Todd B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Boron borylation Carbon monoxide Carbonyls Chemical bonds Chemical reactions Cleavage cluster compounds Coordination compounds Cross coupling Ductile-brittle transition Enrichment Ethane Fracture mechanics Ligands Metal complexes Metals Methane Reaction products Reagents Ruthenium
Online-Zugang:	Volltext
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