Gallium Trihalide Catalyzed Sequential Addition of Two Different Carbon Nucleophiles to Esters by Using Silyl Cyanide and Ketene Silyl Acetals

A sequential addition of silyl cyanide and ketene silyl acetals to esters was achieved by a gallium trihalide catalyst to produce β‐cyano‐β‐siloxy esters. This is the first example of the sequential addition of two different carbon nucleophiles to esters. The employment of lactones provided α,α‐disu...

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Veröffentlicht in:	Chemistry : a European journal 2014-09, Vol.20 (37), p.11664-11668
Hauptverfasser:	Inamoto, Yoshihiro, Kaga, Yuta, Nishimoto, Yoshihiro, Yasuda, Makoto, Baba, Akio
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetals Beta Carbon Chemistry Cyanides Esters Ethers gallium Ketenes Lactones Nucleophiles silicon synthetic methods
Online-Zugang:	Volltext
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