Counterion Dynamics in an Interpenetrated Coordination Cage Capable of Dissolving AgCl

In solution, the eight BF4− counterions of a positively charged D4‐symmetric interpenetrated [Pd4ligand8]8+ double cage (1) are localized in distinct positions. At low temperatures, one BF4− ion is encapsulated inside the central pocket of the supramolecular structure, two BF4− ions are bound inside...

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