Molecular Daisy Chains: Synthesis and Aggregation Studies of an Amphiphilic Molecular Rod
A water‐soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers. It has been demonstrated that this hermaphroditic compound forms [c2]daisy chains in polar solvent over a wide range...
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| Veröffentlicht in: | Chemistry : a European journal 2013-02, Vol.19 (6), p.2089-2101 |
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| container_issue | 6 |
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| container_title | Chemistry : a European journal |
| container_volume | 19 |
| creator | Rotzler, Jürgen Drayss, Sylvie Hampe, Oliver Häussinger, Daniel Mayor, Marcel |
| description | A water‐soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers. It has been demonstrated that this hermaphroditic compound forms [c2]daisy chains in polar solvent over a wide range of concentrations. Furthermore, evidence for the formation of higher mechanically interlinked oligomers above the critical aggregation concentration has been obtained.
Oligomeric daisy chains: A water‐soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers (see figure). This hermaphroditic compound forms [c2]daisy chains in polar solvents over a wide range of concentrations. Furthermore, evidence for the formation of larger, mechanically interlinked oligomers above the critical aggregation concentration has been obtained. |
| doi_str_mv | 10.1002/chem.201202498 |
| format | Article |
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Oligomeric daisy chains: A water‐soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers (see figure). This hermaphroditic compound forms [c2]daisy chains in polar solvents over a wide range of concentrations. Furthermore, evidence for the formation of larger, mechanically interlinked oligomers above the critical aggregation concentration has been obtained.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201202498</identifier><identifier>PMID: 23297171</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Agglomeration ; amphiphiles ; Binding ; Chemistry ; cyclophanes ; daisy chains ; Formations ; host-guest chemistry ; Oligomers ; self-assembly ; Solvents ; Synthesis (chemistry)</subject><ispartof>Chemistry : a European journal, 2013-02, Vol.19 (6), p.2089-2101</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4448-8c4859b682c0c17bafc181b4a25029a5bdf9d5413adb64932b32f558aa0ef91f3</citedby><cites>FETCH-LOGICAL-c4448-8c4859b682c0c17bafc181b4a25029a5bdf9d5413adb64932b32f558aa0ef91f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201202498$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201202498$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23297171$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rotzler, Jürgen</creatorcontrib><creatorcontrib>Drayss, Sylvie</creatorcontrib><creatorcontrib>Hampe, Oliver</creatorcontrib><creatorcontrib>Häussinger, Daniel</creatorcontrib><creatorcontrib>Mayor, Marcel</creatorcontrib><title>Molecular Daisy Chains: Synthesis and Aggregation Studies of an Amphiphilic Molecular Rod</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>A water‐soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers. It has been demonstrated that this hermaphroditic compound forms [c2]daisy chains in polar solvent over a wide range of concentrations. Furthermore, evidence for the formation of higher mechanically interlinked oligomers above the critical aggregation concentration has been obtained.
Oligomeric daisy chains: A water‐soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers (see figure). This hermaphroditic compound forms [c2]daisy chains in polar solvents over a wide range of concentrations. Furthermore, evidence for the formation of larger, mechanically interlinked oligomers above the critical aggregation concentration has been obtained.</description><subject>Agglomeration</subject><subject>amphiphiles</subject><subject>Binding</subject><subject>Chemistry</subject><subject>cyclophanes</subject><subject>daisy chains</subject><subject>Formations</subject><subject>host-guest chemistry</subject><subject>Oligomers</subject><subject>self-assembly</subject><subject>Solvents</subject><subject>Synthesis (chemistry)</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkUtPGzEURi1UBOGx7bKy1A2bCX6ObXZReKRSAInwECvL4_EkpvMI9oza_PsOBELFBulKd3HPd6SrD4DvGA0xQuTYLlw1JAgTRJiSW2CAOcEJFSn_BgZIMZGknKpdsBfjE0JIpZTugF1CiRJY4AF4vGxKZ7vSBHhqfFzB8cL4Op7A2apuFy76CE2dw9F8HtzctL6p4aztcu8ibIr-BEfVcuH7Kb2FH66bJj8A24Upozt82_vg7vzsdjxJptcXv8ajaWIZYzKRlkmuslQSiywWmSksljhjhnBElOFZXqicM0xNnqVMUZJRUnAujUGuULig--Bo7V2G5rlzsdWVj9aVpald00WNhZCISYXx1yiRRNKUv6I_P6FPTRfq_pFXinCpBOqp4ZqyoYkxuEIvg69MWGmM9Es_-qUfvemnD_x403ZZ5fIN_l5ID6g18MeXbvWFTo8nZ5f_y5N11sfW_d1kTfitU0EF1w9XF5rfTmZ8Su71A_0HxbSp6g</recordid><startdate>20130204</startdate><enddate>20130204</enddate><creator>Rotzler, Jürgen</creator><creator>Drayss, Sylvie</creator><creator>Hampe, Oliver</creator><creator>Häussinger, Daniel</creator><creator>Mayor, Marcel</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20130204</creationdate><title>Molecular Daisy Chains: Synthesis and Aggregation Studies of an Amphiphilic Molecular Rod</title><author>Rotzler, Jürgen ; Drayss, Sylvie ; Hampe, Oliver ; Häussinger, Daniel ; Mayor, Marcel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4448-8c4859b682c0c17bafc181b4a25029a5bdf9d5413adb64932b32f558aa0ef91f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Agglomeration</topic><topic>amphiphiles</topic><topic>Binding</topic><topic>Chemistry</topic><topic>cyclophanes</topic><topic>daisy chains</topic><topic>Formations</topic><topic>host-guest chemistry</topic><topic>Oligomers</topic><topic>self-assembly</topic><topic>Solvents</topic><topic>Synthesis (chemistry)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rotzler, Jürgen</creatorcontrib><creatorcontrib>Drayss, Sylvie</creatorcontrib><creatorcontrib>Hampe, Oliver</creatorcontrib><creatorcontrib>Häussinger, Daniel</creatorcontrib><creatorcontrib>Mayor, Marcel</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rotzler, Jürgen</au><au>Drayss, Sylvie</au><au>Hampe, Oliver</au><au>Häussinger, Daniel</au><au>Mayor, Marcel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molecular Daisy Chains: Synthesis and Aggregation Studies of an Amphiphilic Molecular Rod</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2013-02-04</date><risdate>2013</risdate><volume>19</volume><issue>6</issue><spage>2089</spage><epage>2101</epage><pages>2089-2101</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>A water‐soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers. It has been demonstrated that this hermaphroditic compound forms [c2]daisy chains in polar solvent over a wide range of concentrations. Furthermore, evidence for the formation of higher mechanically interlinked oligomers above the critical aggregation concentration has been obtained.
Oligomeric daisy chains: A water‐soluble cyclophane as the loop subunit, monofunctionalized with a molecular rod, has been synthesized to introduce a new binding motif for mechanically interlinked oligomers (see figure). This hermaphroditic compound forms [c2]daisy chains in polar solvents over a wide range of concentrations. Furthermore, evidence for the formation of larger, mechanically interlinked oligomers above the critical aggregation concentration has been obtained.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>23297171</pmid><doi>10.1002/chem.201202498</doi><tpages>13</tpages></addata></record> |
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| ispartof | Chemistry : a European journal, 2013-02, Vol.19 (6), p.2089-2101 |
| issn | 0947-6539 1521-3765 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Agglomeration amphiphiles Binding Chemistry cyclophanes daisy chains Formations host-guest chemistry Oligomers self-assembly Solvents Synthesis (chemistry) |
| title | Molecular Daisy Chains: Synthesis and Aggregation Studies of an Amphiphilic Molecular Rod |
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