Synthesis of Alkylbismuths by Regiodivergent Carbobismuthination of Simple Alkenes

Switchable regioselectivity: This study represents the first carbobismuthination of alkenes achieved by the treatment of an alkene with a bismuth halide and a ketene silyl acetal. This reaction is particularly noteworthy in that a change in the type of halogen on a bismuth atom very easily switched...

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Veröffentlicht in:	Chemistry : a European journal 2013-10, Vol.19 (43), p.14411-14415
Hauptverfasser:	Nishimoto, Yoshihiro, Takeuchi, Midori, Yasuda, Makoto, Baba, Akio
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Bismuth Bismuth halides carbobismuthination Chemistry Halogens ketene silyl acetal Ketenes Synthesis synthetic methods
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description	Switchable regioselectivity: This study represents the first carbobismuthination of alkenes achieved by the treatment of an alkene with a bismuth halide and a ketene silyl acetal. This reaction is particularly noteworthy in that a change in the type of halogen on a bismuth atom very easily switched the regioselectivity (see scheme).
doi_str_mv	10.1002/chem.201302194
format	Article
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subjects	Alkenes Bismuth Bismuth halides carbobismuthination Chemistry Halogens ketene silyl acetal Ketenes Synthesis synthetic methods
title	Synthesis of Alkylbismuths by Regiodivergent Carbobismuthination of Simple Alkenes
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