Multiple Zeolite Structures from One Ionic Liquid Template
This study reports the use of 1‐butyl‐3‐methyl imidazolium methanesulfonate ionic liquid as a template in the synthesis of zeolites. It is found that the silicon source determines the formation of beta (BEA), mordenite framework inverted (MFI), or analcime (ANA) zeolites. Depending on this source, d...
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| Veröffentlicht in: | Chemistry : a European journal 2013-02, Vol.19 (6), p.2122-2130 |
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| container_title | Chemistry : a European journal |
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| creator | Martínez Blanes, José María Szyja, Bartłomiej M. Romero-Sarria, Francisca Centeno, Miguel Ángel Hensen, Emiel J. M. Odriozola, José Antonio Ivanova, Svetlana |
| description | This study reports the use of 1‐butyl‐3‐methyl imidazolium methanesulfonate ionic liquid as a template in the synthesis of zeolites. It is found that the silicon source determines the formation of beta (BEA), mordenite framework inverted (MFI), or analcime (ANA) zeolites. Depending on this source, different preorganized complexes are obtained that drive the formation of the different zeolite structures. In the presence of ethanol, the ionic liquid form preorganized complexes that drive the formation of MFI. In its absence, BEA is obtained. Whereas, the large amount of sodium present when using sodium metasilicate leads to ANA formation. A molecular simulation study of the relative stability of the template‐framework system and location of the template provides further insight into the mechanism of synthesis.
Driven to develop: Three different zeolite families were synthesized by using a short‐chain alkylimidazolium ionic liquid as the template (see figure). The importance of the silicon source, chemical environment, and the template‐gel components in driving the formation of the different zeolite structures are demonstrated by a molecular simulation study and experimental techniques. |
| doi_str_mv | 10.1002/chem.201202556 |
| format | Article |
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Driven to develop: Three different zeolite families were synthesized by using a short‐chain alkylimidazolium ionic liquid as the template (see figure). The importance of the silicon source, chemical environment, and the template‐gel components in driving the formation of the different zeolite structures are demonstrated by a molecular simulation study and experimental techniques.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201202556</identifier><identifier>PMID: 23255393</identifier><identifier>CODEN: CEUJED</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Analytical chemistry ; Chemistry ; Formations ; Ionic liquids ; Ions ; MFI ; molecular modeling ; molecular organization ; Molecular structure ; Silicon ; Simulation ; Sodium ; Zeolites</subject><ispartof>Chemistry : a European journal, 2013-02, Vol.19 (6), p.2122-2130</ispartof><rights>Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4816-c41db373a17b018e6ec184a0c4f92cd2c8a0918e5e9222094fdd704d118a0bce3</citedby><cites>FETCH-LOGICAL-c4816-c41db373a17b018e6ec184a0c4f92cd2c8a0918e5e9222094fdd704d118a0bce3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201202556$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201202556$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23255393$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Martínez Blanes, José María</creatorcontrib><creatorcontrib>Szyja, Bartłomiej M.</creatorcontrib><creatorcontrib>Romero-Sarria, Francisca</creatorcontrib><creatorcontrib>Centeno, Miguel Ángel</creatorcontrib><creatorcontrib>Hensen, Emiel J. M.</creatorcontrib><creatorcontrib>Odriozola, José Antonio</creatorcontrib><creatorcontrib>Ivanova, Svetlana</creatorcontrib><title>Multiple Zeolite Structures from One Ionic Liquid Template</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>This study reports the use of 1‐butyl‐3‐methyl imidazolium methanesulfonate ionic liquid as a template in the synthesis of zeolites. It is found that the silicon source determines the formation of beta (BEA), mordenite framework inverted (MFI), or analcime (ANA) zeolites. Depending on this source, different preorganized complexes are obtained that drive the formation of the different zeolite structures. In the presence of ethanol, the ionic liquid form preorganized complexes that drive the formation of MFI. In its absence, BEA is obtained. Whereas, the large amount of sodium present when using sodium metasilicate leads to ANA formation. A molecular simulation study of the relative stability of the template‐framework system and location of the template provides further insight into the mechanism of synthesis.
Driven to develop: Three different zeolite families were synthesized by using a short‐chain alkylimidazolium ionic liquid as the template (see figure). The importance of the silicon source, chemical environment, and the template‐gel components in driving the formation of the different zeolite structures are demonstrated by a molecular simulation study and experimental techniques.</description><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>Formations</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>MFI</subject><subject>molecular modeling</subject><subject>molecular organization</subject><subject>Molecular structure</subject><subject>Silicon</subject><subject>Simulation</subject><subject>Sodium</subject><subject>Zeolites</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkc9P2zAYhi0EGoXtuuMUiQuXdP4-x3G82yg_pVIOY0LiYqXOF2FImmInAv57XMoqtAsXW7Kf99Fnv4x9Bz4GzvGnvaN2jByQo5T5FhuBREiFyuU2G3GdqTSXQu-yvRDuOec6F-IL20URaaHFiP26HJreLRtKbqlrXE_Jn94Pth88haT2XZtcLSi56BbOJlP3OLgquaZ22ZQ9fWU7ddkE-va-77O_pyfXk_N0enV2Mfk9TW1WQB5XqOZCiRLUnENBOVkospLbrNZoK7RFyXU8l6QRMY5cV5XiWQUQL-aWxD47XHuXvnscKPSmdcFS05QL6oZgQKmCZwAy-xzFAguhJWJED_5D77vBL-JD3iiUGvhKOF5T1ncheKrN0ru29C8GuFkVYFYFmE0BMfDjXTvMW6o2-L8fj4BeA0-uoZdPdGZyfnL5UZ6usy709LzJlv7B5EooaW5mZ-ZGZjN9NENzLF4Bni2ecg</recordid><startdate>20130204</startdate><enddate>20130204</enddate><creator>Martínez Blanes, José María</creator><creator>Szyja, Bartłomiej M.</creator><creator>Romero-Sarria, Francisca</creator><creator>Centeno, Miguel Ángel</creator><creator>Hensen, Emiel J. 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M.</au><au>Odriozola, José Antonio</au><au>Ivanova, Svetlana</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multiple Zeolite Structures from One Ionic Liquid Template</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. Eur. J</addtitle><date>2013-02-04</date><risdate>2013</risdate><volume>19</volume><issue>6</issue><spage>2122</spage><epage>2130</epage><pages>2122-2130</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><coden>CEUJED</coden><abstract>This study reports the use of 1‐butyl‐3‐methyl imidazolium methanesulfonate ionic liquid as a template in the synthesis of zeolites. It is found that the silicon source determines the formation of beta (BEA), mordenite framework inverted (MFI), or analcime (ANA) zeolites. Depending on this source, different preorganized complexes are obtained that drive the formation of the different zeolite structures. In the presence of ethanol, the ionic liquid form preorganized complexes that drive the formation of MFI. In its absence, BEA is obtained. Whereas, the large amount of sodium present when using sodium metasilicate leads to ANA formation. A molecular simulation study of the relative stability of the template‐framework system and location of the template provides further insight into the mechanism of synthesis.
Driven to develop: Three different zeolite families were synthesized by using a short‐chain alkylimidazolium ionic liquid as the template (see figure). The importance of the silicon source, chemical environment, and the template‐gel components in driving the formation of the different zeolite structures are demonstrated by a molecular simulation study and experimental techniques.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>23255393</pmid><doi>10.1002/chem.201202556</doi><tpages>9</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Analytical chemistry Chemistry Formations Ionic liquids Ions MFI molecular modeling molecular organization Molecular structure Silicon Simulation Sodium Zeolites |
| title | Multiple Zeolite Structures from One Ionic Liquid Template |
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