3D Nanostructured Conjugated Polymers for Optical Applications
The self assembly of block‐copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4‐ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of so...
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| Veröffentlicht in: | Advanced functional materials 2015-11, Vol.25 (44), p.6900-6905 |
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| container_title | Advanced functional materials |
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| creator | Dehmel, Raphael Nicolas, Alexandre Scherer, Maik R. J. Steiner, Ullrich |
| description | The self assembly of block‐copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4‐ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of solvents and electrolytes allows the excellent replication of the initial self‐assembled morphology into self‐supporting gyroidal conjugated polymer networks. The nanostructured films are employed to fabricate electrochromic devices, exhibiting excellent color contrast upon switching, with fast switching speeds. The versatility and reliability of this method are demonstrated by the creation of switchable Fresnel zone plates, with which the focussing of light can be switched on and off.
Mesoporous networks of conjugated polymers were synthesized by electropolymerisation into templates created by block‐copolymer self‐assembly. The nanostructured conductive polymer layers were employed to manufacture electrochromic zone‐plates that reversibly switch on and off the focussing of light. |
| doi_str_mv | 10.1002/adfm.201502392 |
| format | Article |
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Mesoporous networks of conjugated polymers were synthesized by electropolymerisation into templates created by block‐copolymer self‐assembly. The nanostructured conductive polymer layers were employed to manufacture electrochromic zone‐plates that reversibly switch on and off the focussing of light.</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.201502392</identifier><language>eng</language><publisher>Blackwell Publishing Ltd</publisher><subject>Electrochromism ; fresnel zone plates ; Morphology ; Nanostructure ; nanostructured conjugated polymers ; Networks ; polymer self-assembly ; Self assembly ; Switching ; Switching theory ; Three dimensional</subject><ispartof>Advanced functional materials, 2015-11, Vol.25 (44), p.6900-6905</ispartof><rights>2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4002-7af0a78fe754f93ce7aa442f68679601242be7c9d8f59e093d26f1b64758a0183</citedby><cites>FETCH-LOGICAL-c4002-7af0a78fe754f93ce7aa442f68679601242be7c9d8f59e093d26f1b64758a0183</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadfm.201502392$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadfm.201502392$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Dehmel, Raphael</creatorcontrib><creatorcontrib>Nicolas, Alexandre</creatorcontrib><creatorcontrib>Scherer, Maik R. J.</creatorcontrib><creatorcontrib>Steiner, Ullrich</creatorcontrib><title>3D Nanostructured Conjugated Polymers for Optical Applications</title><title>Advanced functional materials</title><addtitle>Adv. Funct. Mater</addtitle><description>The self assembly of block‐copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4‐ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of solvents and electrolytes allows the excellent replication of the initial self‐assembled morphology into self‐supporting gyroidal conjugated polymer networks. The nanostructured films are employed to fabricate electrochromic devices, exhibiting excellent color contrast upon switching, with fast switching speeds. The versatility and reliability of this method are demonstrated by the creation of switchable Fresnel zone plates, with which the focussing of light can be switched on and off.
Mesoporous networks of conjugated polymers were synthesized by electropolymerisation into templates created by block‐copolymer self‐assembly. The nanostructured conductive polymer layers were employed to manufacture electrochromic zone‐plates that reversibly switch on and off the focussing of light.</description><subject>Electrochromism</subject><subject>fresnel zone plates</subject><subject>Morphology</subject><subject>Nanostructure</subject><subject>nanostructured conjugated polymers</subject><subject>Networks</subject><subject>polymer self-assembly</subject><subject>Self assembly</subject><subject>Switching</subject><subject>Switching theory</subject><subject>Three dimensional</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkD1PwzAQhi0EEqWwMmdkSfHZiZ0sSFVLC6IfDCC6Wa5jo5QkDnYi6L8nVVDFxnTv8D6nuweha8AjwJjcysyUI4IhxoSm5AQNgAELKSbJ6THD5hxdeL_DGDin0QDd0WmwkpX1jWtV0zqdBRNb7dp32XTx2Rb7UjsfGOuCdd3kShbBuK6LLjS5rfwlOjOy8Prqdw7R6-z-ZfIQLtbzx8l4EaqoOy3k0mDJE6N5HJmUKs2ljCJiWMJ4yjCQiGw1V2mWmDjVOKUZYQa2LOJxIjEkdIhu-r21s5-t9o0oc690UchK29aL7psEUw5AuuqorypnvXfaiNrlpXR7AVgcRImDKHEU1QFpD3zlhd7_0xbj6Wz5lw17NveN_j6y0n0IximPxdtqLjazKczpEsQT_QEH-Hq8</recordid><startdate>20151125</startdate><enddate>20151125</enddate><creator>Dehmel, Raphael</creator><creator>Nicolas, Alexandre</creator><creator>Scherer, Maik R. J.</creator><creator>Steiner, Ullrich</creator><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20151125</creationdate><title>3D Nanostructured Conjugated Polymers for Optical Applications</title><author>Dehmel, Raphael ; Nicolas, Alexandre ; Scherer, Maik R. J. ; Steiner, Ullrich</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4002-7af0a78fe754f93ce7aa442f68679601242be7c9d8f59e093d26f1b64758a0183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Electrochromism</topic><topic>fresnel zone plates</topic><topic>Morphology</topic><topic>Nanostructure</topic><topic>nanostructured conjugated polymers</topic><topic>Networks</topic><topic>polymer self-assembly</topic><topic>Self assembly</topic><topic>Switching</topic><topic>Switching theory</topic><topic>Three dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dehmel, Raphael</creatorcontrib><creatorcontrib>Nicolas, Alexandre</creatorcontrib><creatorcontrib>Scherer, Maik R. J.</creatorcontrib><creatorcontrib>Steiner, Ullrich</creatorcontrib><collection>Istex</collection><collection>Wiley Online Library (Open Access Collection)</collection><collection>Wiley Online Library (Open Access Collection)</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dehmel, Raphael</au><au>Nicolas, Alexandre</au><au>Scherer, Maik R. J.</au><au>Steiner, Ullrich</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>3D Nanostructured Conjugated Polymers for Optical Applications</atitle><jtitle>Advanced functional materials</jtitle><addtitle>Adv. Funct. Mater</addtitle><date>2015-11-25</date><risdate>2015</risdate><volume>25</volume><issue>44</issue><spage>6900</spage><epage>6905</epage><pages>6900-6905</pages><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>The self assembly of block‐copolymers into the gyroid morphology is replicated into 3D nanostructured conjugated polymers. Voided styrenic gyroidal networks are used as scaffolds for the electrodeposition of two poly(3,4‐ethylenedioxythiophene) derivatives and poly(pyrrole). The careful choice of solvents and electrolytes allows the excellent replication of the initial self‐assembled morphology into self‐supporting gyroidal conjugated polymer networks. The nanostructured films are employed to fabricate electrochromic devices, exhibiting excellent color contrast upon switching, with fast switching speeds. The versatility and reliability of this method are demonstrated by the creation of switchable Fresnel zone plates, with which the focussing of light can be switched on and off.
Mesoporous networks of conjugated polymers were synthesized by electropolymerisation into templates created by block‐copolymer self‐assembly. The nanostructured conductive polymer layers were employed to manufacture electrochromic zone‐plates that reversibly switch on and off the focussing of light.</abstract><pub>Blackwell Publishing Ltd</pub><doi>10.1002/adfm.201502392</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| source | Access via Wiley Online Library |
| subjects | Electrochromism fresnel zone plates Morphology Nanostructure nanostructured conjugated polymers Networks polymer self-assembly Self assembly Switching Switching theory Three dimensional |
| title | 3D Nanostructured Conjugated Polymers for Optical Applications |
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