An Unsymmetrically π-Extended Porphyrin-Based Single-Crystal Field-Effect Transistor and Its Anisotropic Carrier-Transport Behavior
Anisotropic charge transport: Single‐crystal organic field‐effect transistor devices derived from aggregates of thiophene‐appended porphyrins display very high mobility (0.27 cm2 V−1 s−1). This behavior is due to staircase stacking of the porphyrins with distances between layers of 3.17(7) Å. Furthe...
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Veröffentlicht in: | Chemistry : a European journal 2013-02, Vol.19 (7), p.2247-2251 |
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container_title | Chemistry : a European journal |
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creator | Choi, Soojung Chae, Seung Hyun Hoang, Mai Ha Kim, Kyung Hwan Huh, Jung A Kim, Youngmee Kim, Sung-Jin Choi, Dong Hoon Lee, Suk Joong |
description | Anisotropic charge transport: Single‐crystal organic field‐effect transistor devices derived from aggregates of thiophene‐appended porphyrins display very high mobility (0.27 cm2 V−1 s−1). This behavior is due to staircase stacking of the porphyrins with distances between layers of 3.17(7) Å. Furthermore, the charge‐transport behavior is anisotropic owing to an anisotropic molecular arrangement in the single‐crystal microplates. |
doi_str_mv | 10.1002/chem.201202894 |
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KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4164-30d56f91860f10f4a7f5df7171f65faf07f6fad329dbf2ff09ca4dea49f347453</citedby><cites>FETCH-LOGICAL-c4164-30d56f91860f10f4a7f5df7171f65faf07f6fad329dbf2ff09ca4dea49f347453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201202894$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201202894$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23281095$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Choi, Soojung</creatorcontrib><creatorcontrib>Chae, Seung Hyun</creatorcontrib><creatorcontrib>Hoang, Mai Ha</creatorcontrib><creatorcontrib>Kim, Kyung Hwan</creatorcontrib><creatorcontrib>Huh, Jung A</creatorcontrib><creatorcontrib>Kim, Youngmee</creatorcontrib><creatorcontrib>Kim, Sung-Jin</creatorcontrib><creatorcontrib>Choi, Dong Hoon</creatorcontrib><creatorcontrib>Lee, Suk Joong</creatorcontrib><title>An Unsymmetrically π-Extended Porphyrin-Based Single-Crystal Field-Effect Transistor and Its Anisotropic Carrier-Transport Behavior</title><title>Chemistry : a European journal</title><addtitle>Chem. Eur. J</addtitle><description>Anisotropic charge transport: Single‐crystal organic field‐effect transistor devices derived from aggregates of thiophene‐appended porphyrins display very high mobility (0.27 cm2 V−1 s−1). This behavior is due to staircase stacking of the porphyrins with distances between layers of 3.17(7) Å. Furthermore, the charge‐transport behavior is anisotropic owing to an anisotropic molecular arrangement in the single‐crystal microplates.</description><subject>Aggregates</subject><subject>anisotropic behavior</subject><subject>Anisotropy</subject><subject>carrier transport</subject><subject>Charge transport</subject><subject>Field effect transistors</subject><subject>Porphyrins</subject><subject>Semiconductor devices</subject><subject>semiconductors</subject><subject>Single crystals</subject><subject>Stacking</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkTtvFDEURi1ERJZAS4lc0njx2-NyM9psgpKARB4SjeWMbdYwr9izkOko-H_8pUzYsKJLdXWl853mAPCG4DnBmL6v1r6ZU0wopoXmz8CMCEoQU1I8BzOsuUJSML0PXub8DWOsJWMvwD5ltCBYixn4vWjhZZvHpvFDipWt6xH--YWWd4NvnXfwU5f69Zhiiw5tnv7Psf1ae1SmMQ-2hkfR1w4tQ_DVAC-SbXPMQ5egbR08GTJctDF3Q-r6WMHSphR9Qn-xvksDPPRr-yN26RXYC7bO_vXjPQCXR8uL8hidflydlItTVHEiOWLYCRk0KSQOBAduVRAuKKJIkCLYgFWQwTpGtbsJNASsK8udt1wHxhUX7AC823r71N1ufB5ME3Pl69q2vttkQ5QqMBOYyqdRWnCqcaH1hM63aJW6nJMPpk-xsWk0BJuHSOYhktlFmgZvH92bm8a7Hf6vygToLfAz1n58QmfK4-XZ_3K03U4h_N1ua9N3IxVTwlyfr4z88OXqWhdXZsXuAf4hsBI</recordid><startdate>20130211</startdate><enddate>20130211</enddate><creator>Choi, Soojung</creator><creator>Chae, Seung Hyun</creator><creator>Hoang, Mai Ha</creator><creator>Kim, Kyung Hwan</creator><creator>Huh, Jung A</creator><creator>Kim, Youngmee</creator><creator>Kim, Sung-Jin</creator><creator>Choi, Dong Hoon</creator><creator>Lee, Suk Joong</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130211</creationdate><title>An Unsymmetrically π-Extended Porphyrin-Based Single-Crystal Field-Effect Transistor and Its Anisotropic Carrier-Transport Behavior</title><author>Choi, Soojung ; Chae, Seung Hyun ; Hoang, Mai Ha ; Kim, Kyung Hwan ; Huh, Jung A ; Kim, Youngmee ; Kim, Sung-Jin ; Choi, Dong Hoon ; Lee, Suk Joong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4164-30d56f91860f10f4a7f5df7171f65faf07f6fad329dbf2ff09ca4dea49f347453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Aggregates</topic><topic>anisotropic behavior</topic><topic>Anisotropy</topic><topic>carrier transport</topic><topic>Charge transport</topic><topic>Field effect transistors</topic><topic>Porphyrins</topic><topic>Semiconductor devices</topic><topic>semiconductors</topic><topic>Single crystals</topic><topic>Stacking</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Choi, Soojung</creatorcontrib><creatorcontrib>Chae, Seung Hyun</creatorcontrib><creatorcontrib>Hoang, Mai Ha</creatorcontrib><creatorcontrib>Kim, Kyung Hwan</creatorcontrib><creatorcontrib>Huh, Jung A</creatorcontrib><creatorcontrib>Kim, Youngmee</creatorcontrib><creatorcontrib>Kim, Sung-Jin</creatorcontrib><creatorcontrib>Choi, Dong Hoon</creatorcontrib><creatorcontrib>Lee, Suk Joong</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Choi, Soojung</au><au>Chae, Seung Hyun</au><au>Hoang, Mai Ha</au><au>Kim, Kyung Hwan</au><au>Huh, Jung A</au><au>Kim, Youngmee</au><au>Kim, Sung-Jin</au><au>Choi, Dong Hoon</au><au>Lee, Suk Joong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Unsymmetrically π-Extended Porphyrin-Based Single-Crystal Field-Effect Transistor and Its Anisotropic Carrier-Transport Behavior</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chem. 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source | Wiley Online Library Journals Frontfile Complete |
subjects | Aggregates anisotropic behavior Anisotropy carrier transport Charge transport Field effect transistors Porphyrins Semiconductor devices semiconductors Single crystals Stacking |
title | An Unsymmetrically π-Extended Porphyrin-Based Single-Crystal Field-Effect Transistor and Its Anisotropic Carrier-Transport Behavior |
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