An Unsymmetrically π-Extended Porphyrin-Based Single-Crystal Field-Effect Transistor and Its Anisotropic Carrier-Transport Behavior

Anisotropic charge transport: Single‐crystal organic field‐effect transistor devices derived from aggregates of thiophene‐appended porphyrins display very high mobility (0.27 cm2 V−1 s−1). This behavior is due to staircase stacking of the porphyrins with distances between layers of 3.17(7) Å. Furthe...

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Veröffentlicht in:Chemistry : a European journal 2013-02, Vol.19 (7), p.2247-2251
Hauptverfasser: Choi, Soojung, Chae, Seung Hyun, Hoang, Mai Ha, Kim, Kyung Hwan, Huh, Jung A, Kim, Youngmee, Kim, Sung-Jin, Choi, Dong Hoon, Lee, Suk Joong
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container_end_page 2251
container_issue 7
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container_title Chemistry : a European journal
container_volume 19
creator Choi, Soojung
Chae, Seung Hyun
Hoang, Mai Ha
Kim, Kyung Hwan
Huh, Jung A
Kim, Youngmee
Kim, Sung-Jin
Choi, Dong Hoon
Lee, Suk Joong
description Anisotropic charge transport: Single‐crystal organic field‐effect transistor devices derived from aggregates of thiophene‐appended porphyrins display very high mobility (0.27 cm2 V−1 s−1). This behavior is due to staircase stacking of the porphyrins with distances between layers of 3.17(7) Å. Furthermore, the charge‐transport behavior is anisotropic owing to an anisotropic molecular arrangement in the single‐crystal microplates.
doi_str_mv 10.1002/chem.201202894
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source Wiley Online Library Journals Frontfile Complete
subjects Aggregates
anisotropic behavior
Anisotropy
carrier transport
Charge transport
Field effect transistors
Porphyrins
Semiconductor devices
semiconductors
Single crystals
Stacking
title An Unsymmetrically π-Extended Porphyrin-Based Single-Crystal Field-Effect Transistor and Its Anisotropic Carrier-Transport Behavior
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