An Efficient Method for Sterically Demanding Suzuki-Miyaura Coupling Reactions

An efficient method for sterically demanding Suzuki–Miyaura coupling reactions has been developed with two catalysts, Pd/BI‐DIME (see scheme) and Pd/phenanthrene‐based ligand. The Pd/BI‐DIME catalyst facilitates the syntheses of extremely hindered biaryls bearing ortho‐isopropyl substituents. The ot...

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Veröffentlicht in:	Chemistry : a European journal 2013-02, Vol.19 (7), p.2261-2265
Hauptverfasser:	Zhao, Qing, Li, Chengxi, Senanayake, Chris H., Tang, Wenjun
Format:	Artikel
Sprache:	eng
Schlagworte:	Bearing biaryls Biphenyl Compounds - chemistry Boron Compounds - chemistry Catalysis Catalysts Chemical reactions Chemistry cross-coupling Cross-Linking Reagents - chemistry homogeneous catalysis Ligands Molecular Structure Palladium Palladium - chemistry Phenanthrenes - chemistry steric hindrance Synthesis
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