Removal of chromium(VI) from aqueous solution using iron orthophosphate that is synthesized by different methods
The adsorption of chromium(VI) from aqueous solutions was studied on iron orthophosphate synthesized by solution, solution combustion, and solid state method. The properties of samples were determined by X-ray powder diffraction, nitrogen adsorption, and scanning electron microscope. The adsorption...
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Veröffentlicht in: | Desalination and water treatment 2015-11, Vol.56 (7), p.1855-1862 |
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description | The adsorption of chromium(VI) from aqueous solutions was studied on iron orthophosphate synthesized by solution, solution combustion, and solid state method. The properties of samples were determined by X-ray powder diffraction, nitrogen adsorption, and scanning electron microscope. The adsorption of chromium(VI) on solution combustion synthesized iron orthophosphate was found to be maximum in comparison to the other synthesis approaches. The equilibrium data for the adsorption of chromium were analyzed in Langmuir and Freundlich isotherm models. The adsorption process could be described by pseudo-second-order kinetic model. Iron orthophosphate was the most active at pH 2. The maximum adsorption capacity for iron orthophosphate synthesized by solution combustion, solid state, and solution method are 21, 13.2, and 12.1 mg/g at 100 ppm chromium concentration with 1 g/L adsorbent dose for 2 h. Iron orthophosphate is cheap and easy to operate for adsorption of hexavalent chromium(VI) from wastewater. |
doi_str_mv | 10.1080/19443994.2014.958102 |
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The properties of samples were determined by X-ray powder diffraction, nitrogen adsorption, and scanning electron microscope. The adsorption of chromium(VI) on solution combustion synthesized iron orthophosphate was found to be maximum in comparison to the other synthesis approaches. The equilibrium data for the adsorption of chromium were analyzed in Langmuir and Freundlich isotherm models. The adsorption process could be described by pseudo-second-order kinetic model. Iron orthophosphate was the most active at pH 2. The maximum adsorption capacity for iron orthophosphate synthesized by solution combustion, solid state, and solution method are 21, 13.2, and 12.1 mg/g at 100 ppm chromium concentration with 1 g/L adsorbent dose for 2 h. Iron orthophosphate is cheap and easy to operate for adsorption of hexavalent chromium(VI) from wastewater.</description><identifier>ISSN: 1944-3986</identifier><identifier>ISSN: 1944-3994</identifier><identifier>EISSN: 1944-3986</identifier><identifier>DOI: 10.1080/19443994.2014.958102</identifier><language>eng</language><publisher>Abingdon: Elsevier Inc</publisher><subject>Adsorption ; Aqueous solutions ; Chromium ; Chromium(VI) ; Combustion ; Iron ; Iron phosphate ; Mathematical models ; Scanning electron microscopy ; Solid state</subject><ispartof>Desalination and water treatment, 2015-11, Vol.56 (7), p.1855-1862</ispartof><rights>2014 Elsevier Inc.</rights><rights>2014 Balaban Desalination Publications. 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The properties of samples were determined by X-ray powder diffraction, nitrogen adsorption, and scanning electron microscope. The adsorption of chromium(VI) on solution combustion synthesized iron orthophosphate was found to be maximum in comparison to the other synthesis approaches. The equilibrium data for the adsorption of chromium were analyzed in Langmuir and Freundlich isotherm models. The adsorption process could be described by pseudo-second-order kinetic model. Iron orthophosphate was the most active at pH 2. The maximum adsorption capacity for iron orthophosphate synthesized by solution combustion, solid state, and solution method are 21, 13.2, and 12.1 mg/g at 100 ppm chromium concentration with 1 g/L adsorbent dose for 2 h. Iron orthophosphate is cheap and easy to operate for adsorption of hexavalent chromium(VI) from wastewater.</description><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Chromium</subject><subject>Chromium(VI)</subject><subject>Combustion</subject><subject>Iron</subject><subject>Iron phosphate</subject><subject>Mathematical models</subject><subject>Scanning electron microscopy</subject><subject>Solid state</subject><issn>1944-3986</issn><issn>1944-3994</issn><issn>1944-3986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkc1q3DAUhU1JIEOaN8hCkE26mKl-LWtTKCFtA4FACNkKWb6qNdiWI8mBydNXZlooXYRqIR2J7x44OlV1SfCO4AZ_JopzphTfUUz4TomGYPqh2qzPW6aa-uQvfVZdpLTHZQkuBaeban6EMbyaAQWHbB_D6Jfx-vnuE3JFI_OyQFgSSmFYsg8TWpKffiIfiwwx92HuQ5p7kwHlsiNf0MOUe0j-DTrUHlDnnYMIU0YjFL5LH6tTZ4YEF7_P8-rp2-3TzY_t_cP3u5uv91vLJc5b4IJip4ShElNHO4WNsVALxlnbKGt5V7ctJmK9gpOU1ECVknUNyuG6ZefV9dF2jqGESFmPPlkYBjOtiTSRssGMMYz_AxWE0kYyWtCrf9B9WOJUchSKimJIJSsUP1I2hpQiOD1HP5p40ATrtTP9pzO9dqaPnZWxL8cxKN_y6iHqZD1MFjofwWbdBf--wS94IJ0M</recordid><startdate>20151113</startdate><enddate>20151113</enddate><creator>Baykan, Demet</creator><creator>Aytekin, Bilsen</creator><creator>Oztas, Nursen Altuntas</creator><general>Elsevier Inc</general><general>Elsevier Limited</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7QL</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7TN</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>FR3</scope><scope>H96</scope><scope>H97</scope><scope>KR7</scope><scope>L.G</scope><scope>M7N</scope><scope>P64</scope><scope>SOI</scope></search><sort><creationdate>20151113</creationdate><title>Removal of chromium(VI) from aqueous solution using iron orthophosphate that is synthesized by different methods</title><author>Baykan, Demet ; Aytekin, Bilsen ; Oztas, Nursen Altuntas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c470t-e4520f95a2702f2d90aace65343b89cc4d6bb01543b8ef7216e299766e9f06b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Chromium</topic><topic>Chromium(VI)</topic><topic>Combustion</topic><topic>Iron</topic><topic>Iron phosphate</topic><topic>Mathematical models</topic><topic>Scanning electron microscopy</topic><topic>Solid state</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baykan, Demet</creatorcontrib><creatorcontrib>Aytekin, Bilsen</creatorcontrib><creatorcontrib>Oztas, Nursen Altuntas</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Oceanic Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Desalination and water treatment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baykan, Demet</au><au>Aytekin, Bilsen</au><au>Oztas, Nursen Altuntas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal of chromium(VI) from aqueous solution using iron orthophosphate that is synthesized by different methods</atitle><jtitle>Desalination and water treatment</jtitle><date>2015-11-13</date><risdate>2015</risdate><volume>56</volume><issue>7</issue><spage>1855</spage><epage>1862</epage><pages>1855-1862</pages><issn>1944-3986</issn><issn>1944-3994</issn><eissn>1944-3986</eissn><abstract>The adsorption of chromium(VI) from aqueous solutions was studied on iron orthophosphate synthesized by solution, solution combustion, and solid state method. The properties of samples were determined by X-ray powder diffraction, nitrogen adsorption, and scanning electron microscope. The adsorption of chromium(VI) on solution combustion synthesized iron orthophosphate was found to be maximum in comparison to the other synthesis approaches. The equilibrium data for the adsorption of chromium were analyzed in Langmuir and Freundlich isotherm models. The adsorption process could be described by pseudo-second-order kinetic model. Iron orthophosphate was the most active at pH 2. The maximum adsorption capacity for iron orthophosphate synthesized by solution combustion, solid state, and solution method are 21, 13.2, and 12.1 mg/g at 100 ppm chromium concentration with 1 g/L adsorbent dose for 2 h. Iron orthophosphate is cheap and easy to operate for adsorption of hexavalent chromium(VI) from wastewater.</abstract><cop>Abingdon</cop><pub>Elsevier Inc</pub><doi>10.1080/19443994.2014.958102</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Adsorption Aqueous solutions Chromium Chromium(VI) Combustion Iron Iron phosphate Mathematical models Scanning electron microscopy Solid state |
title | Removal of chromium(VI) from aqueous solution using iron orthophosphate that is synthesized by different methods |
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