A New Family of Trinuclear Nickel(II) Complexes as Single-Molecule Magnets

Three new trinuclear nickel (II) complexes with the general composition [Ni3L3(OH)(X)](ClO4) have been prepared in which X=Cl− (1), OCN− (2), or N3− (3) and HL is the tridentate N,N,O donor Schiff base ligand 2‐[(3‐dimethylaminopropylimino)methyl]phenol. Single‐crystal structural analyses revealed t...

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Veröffentlicht in:	Chemistry : a European journal 2013-03, Vol.19 (12), p.3943-3953
Hauptverfasser:	Biswas, Rituparna, Ida, Yumi, Baker, Michael L., Biswas, Saptarshi, Kar, Paramita, Nojiri, Hiroyuki, Ishida, Takayuki, Ghosh, Ashutosh
Format:	Artikel
Sprache:	eng
Schlagworte:	Anisotropy Atoms & subatomic particles Chemistry EPR spectroscopy Exchange Ferromagnetism magnetic properties Magnetization Magnets Nickel Polyhedrons Schiff bases Spectra X-ray diffraction
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