A Rational Approach Towards a New Ferrocenyl Pyrrolidine for Stereoselective Enamine Catalysis

Ironing out the details: Proline and pyrrolidine derivatives (Hayashi– Jørgensen catalysts) are considered “work horses” in organocatalysis. This report describes a new effective ferrocenyl pyrrolidine catalyst that is able to perform well in benchmark organocatalytic reactions (see figure). The fer...

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Veröffentlicht in:	Chemistry : a European journal 2013-06, Vol.19 (24), p.7696-7700
Hauptverfasser:	Petruzziello, Diego, Stenta, Marco, Mazzanti, Andrea, Cozzi, Pier Giorgio
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines - chemistry Benchmarking Catalysis Catalysts Chemistry Derivatives Drawing and ironing enamines ferrocene Ferrocenes Ferrous Compounds - chemical synthesis Ferrous Compounds - chemistry Horses Ligands Molecular Structure nitro-Michael reaction organocatalysis Proline - analogs & derivatives Proline - chemical synthesis Proline - chemistry pyrrolidine Pyrrolidines - chemical synthesis Pyrrolidines - chemistry Stereoisomerism
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