Palladium-Catalyzed Coupling Reaction of Perfluoroarenes with Diarylzinc Compounds

This report describes the first Pd0‐catalyzed cross‐coupling of hexafluorobenzene (C6F6) with diarylzinc compounds to give a variety of pentafluorophenyl arenes. This reaction could be applied to other perfluoroarenes, such as octafluorotoluene, pentafluoropyridine, and perfluoronaphthalene, to give...

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Veröffentlicht in:	Chemistry : a European journal 2014-02, Vol.20 (7), p.2040-2048
Hauptverfasser:	Ohashi, Masato, Doi, Ryohei, Ogoshi , Sensuke
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Catalysis Catalysts Chemical reactions Chemistry Cross coupling CF activation Iodides Ligands Lithium palladium perfluoroarenes reaction mechanisms
Online-Zugang:	Volltext
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