Solvatochromic Pyrene Analogues of Prodan Exhibiting Extremely High Fluorescence Quantum Yields in Apolar and Polar Solvents

True colors: Novel pyrene analogues of Prodan exhibit outstanding photophysical properties with remarkably high fluorescence quantum yield (QY) in solvents ranging from apolar hexane to polar methanol (see figure). This is accompanied by strong solvatochromism and large Stokes shifts. These properti...

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Veröffentlicht in:Chemistry : a European journal 2013-07, Vol.19 (30), p.9760-9765
Hauptverfasser: Niko, Yosuke, Kawauchi, Susumu, Konishi, Gen-ichi
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container_issue 30
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container_title Chemistry : a European journal
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creator Niko, Yosuke
Kawauchi, Susumu
Konishi, Gen-ichi
description True colors: Novel pyrene analogues of Prodan exhibit outstanding photophysical properties with remarkably high fluorescence quantum yield (QY) in solvents ranging from apolar hexane to polar methanol (see figure). This is accompanied by strong solvatochromism and large Stokes shifts. These properties have not been previously achieved in enormous solvatochromic dyes, but are quite useful for emitting materials and imaging tools.
doi_str_mv 10.1002/chem.201301020
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source Wiley Online Library - AutoHoldings Journals; MEDLINE
subjects 2-Naphthylamine - analogs & derivatives
2-Naphthylamine - chemical synthesis
2-Naphthylamine - chemistry
Chemistry
Dyes
Emittance
Fluid flow
Fluorescence
fluorescence probes
Fluorescent Dyes - chemical synthesis
Fluorescent Dyes - chemistry
Hexanes
Methyl alcohol
prodan
Pyrenes
Pyrenes - chemical synthesis
Pyrenes - chemistry
solvatochromism
Solvents
Stokes shift
title Solvatochromic Pyrene Analogues of Prodan Exhibiting Extremely High Fluorescence Quantum Yields in Apolar and Polar Solvents
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